Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Conspectus Transition-metal-catalyzed cross-coupling reactions represent a most powerful
tool for the rapid construction of C–C and C–X bonds available to synthetic chemists …

Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …

We review here new developments in decreasing the catalyst loadings in palladium‐
catalyzed C–C bond‐formation reactions to mol ppm or mol ppb levels. This decreases the …

N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

Catalysis of silver nanoparticles, among the metal-based nanoparticles, has been of great
interest in organic synthesis and has expanded rapidly in the past ten years because of …

In this Minireview, the synthesis of amines by the amination of alcohols, by means of the so‐
called borrowing hydrogen methodology, is presented. Compared to other synthetic …

This critical review is devoted to semiconducting and high spin polymers which are of great
scientific interest in view of further development of the organic electronics and the emerging …