The surface chemistry of cerium oxide

DR Mullins - Surface Science Reports, 2015 - Elsevier
This review covers the structure of, and chemical reactions on, well-defined cerium oxide
surfaces. Ceria, or mixed oxides containing ceria, are critical components in automotive …

Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals

S Chen, F Xiong, W Huang - Surface Science Reports, 2019 - Elsevier
Fundamental understandings of surface chemistry and catalysis of solid catalysts are of
great importance for the developments of efficient catalysts and corresponding catalytic …

Epitaxial growth and properties of thin film oxides

SA Chambers - Surface science reports, 2000 - Elsevier
Oxide film growth by molecular beam epitaxy for the purpose of preparing metal oxides for
surface science studies is discussed and reviewed. Critical issues such as the choice of …

Surface properties of from first principles

NV Skorodumova, M Baudin, K Hermansson - Physical Review B, 2004 - APS
The surface energies and electronic structure of (111),(110), and (100) surfaces of CeO 2
have been studied using the first-principles projector augmented-wave method within the …

Water Dissociation on CeO2(100) and CeO2(111) Thin Films

DR Mullins, PM Albrecht, TL Chen… - The Journal of …, 2012 - ACS Publications
This study reports and compares the adsorption and dissociation of water on oxidized and
reduced CeO2 (100) and CeO2 (111) thin films. Water adsorbs dissociatively on both …

Strongly enhanced oxygen ion transport through samarium-doped CeO2 nanopillars in nanocomposite films

SM Yang, S Lee, J Jian, W Zhang, P Lu, Q Jia… - Nature …, 2015 - nature.com
Enhancement of oxygen ion conductivity in oxides is important for low-temperature (< 500°
C) operation of solid oxide fuel cells, sensors and other ionotronic devices. While huge ion …

Surface refaceting mechanism on cubic ceria

C Yang, M Capdevila-Cortada, C Dong… - The journal of …, 2020 - ACS Publications
Polar surfaces of solid oxides are intrinsically unstable and tend to reconstruct due to the
diverging electrostatic energy and thus often exhibit unique physical and chemical …

Entropic contributions enhance polarity compensation for CeO2(100) surfaces

M Capdevila-Cortada, N López - Nature materials, 2017 - nature.com
Surface structure controls the physical and chemical response of materials. Surface polar
terminations are appealing because of their unusual properties but they are intrinsically …

Ionic Conductivity Increased by Two Orders of Magnitude in Micrometer-Thick Vertical Yttria-Stabilized ZrO2 Nanocomposite Films

S Lee, W Zhang, F Khatkhatay, H Wang, Q Jia… - Nano …, 2015 - ACS Publications
We design and create a unique cell geometry of templated micrometer-thick epitaxial
nanocomposite films which contain∼ 20 nm diameter yttria-stabilized ZrO2 (YSZ) …

Electronic and Chemical Properties of Ce0.8Zr0.2O2(111) Surfaces:  Photoemission, XANES, Density-Functional, and NO2 Adsorption Studies

G Liu, JA Rodriguez, J Hrbek, J Dvorak… - The Journal of …, 2001 - ACS Publications
Synchrotron-based high-resolution photoemission, conventional X-ray (Mg Kα)
photoemission (XPS), X-ray absorption near-edge spectroscopy (XANES), and first …