Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009 - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

Metal nitride cluster fullerenes: their current state and future prospects

L Dunsch, S Yang - Small, 2007 - Wiley Online Library
The world of endohedral fullerenes was significantly enlarged over the past seven years by
the cluster fullerenes, which contain structures such as the M2C2 carbides and the M3N …

Bonding in endohedral metallofullerenes as studied by quantum theory of atoms in molecules

AA Popov, L Dunsch - Chemistry–A European Journal, 2009 - Wiley Online Library
Metal–cage and intracluster bonding was studied in detail by quantum theory of atoms in
molecules (QTAIM) for the four major classes of endohedral metallofullerenes (EMFs) …

The beautiful molecule: 30 years of C60 and its derivatives

SFA Acquah, AV Penkova, DA Markelov… - ECS Journal of Solid …, 2017 - iopscience.iop.org
Abstract In 1996 Sir Harold W. Kroto, Robert F. Curl and Richard E. Smalley were honored
with the Nobel Prize in Chemistry for the discovery of fullerenes. The advent of these new …

Trimetallic nitride endohedral metallofullerenes: Reactivity dictated by the encapsulated metal cluster

CM Cardona, A Kitaygorodskiy… - Journal of the American …, 2005 - ACS Publications
The first derivatives of Y3N@ C80 have been synthesized and fully characterized. 1, 3-
Dipolar cycloaddition of N-ethylazomethine ylide yielded mainly the pyrrolidine monoadduct …

[图书][B] Handbook of nanophysics: clusters and fullerenes

KD Sattler - 2010 - taylorfrancis.com
The field of nanoscience was pioneered in the 1980s with the groundbreaking research on
clusters, which later led to the discovery of fullerenes. Handbook of Nanophysics: Clusters …

Bonding between strongly repulsive metal atoms: an oxymoron made real in a confined space of endohedral metallofullerenes

AA Popov, SM Avdoshenko, AM Pendás… - Chemical …, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs) are able to encapsulate up to four metal atoms. In
EMFs, metal atoms are positively charged because of the electron transfer from the …

Endohedral clusterfullerenes—playing with cluster and cage sizes

L Dunsch, S Yang - Physical Chemistry Chemical Physics, 2007 - pubs.rsc.org
The family of endohedral fullerenes was significantly enlarged within the past six years by
the clusterfullerenes containing structures like the M2C2 carbides and the M3N nitrides …

The First Fulleropyrrolidine Derivative of Sc3N@C80:  Pronounced Chemical Shift Differences of the Geminal Protons on the Pyrrolidine Ring

CM Cardona, A Kitaygorodskiy, A Ortiz… - The Journal of …, 2005 - ACS Publications
The first pyrrolidine adduct on Sc3N@ C80 was synthesized and fully characterized.
Addition of the N-ethylazomethine ylide occurs regioselectively on a [5, 6] double bond on …