Reactivity of metal clusters

Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …

Electronic and atomic structure, and magnetism of transition-metal clusters

JA Alonso - Chemical reviews, 2000 - ACS Publications
The free atoms of the transition metals have an incomplete d shell in the ground state or in
excited states of small energy. The d electrons are responsible for the most interesting …

The influence of particle size on the catalytic properties of supported metals

M Che, CO Bennett - Advances in Catalysis, 1989 - Elsevier
Publisher Summary Metals constitute a wide class of catalysts, and because catalysis occurs
on the surface, there is an economic incentive, especially for precious metals, to obtain …

Clusters: Structure, energetics, and dynamics of intermediate states of matter

AW Castleman, KH Bowen - The Journal of Physical Chemistry, 1996 - ACS Publications
The field of cluster research can trace its origins back to the mid-nineteenth century when
early studies of colloids, aerosols, and nucleation phenomena were reported. The field …

Invited review article: laser vaporization cluster sources

MA Duncan - Review of scientific instruments, 2012 - pubs.aip.org
The laser vaporization cluster source has been used for the production of gas phase atomic
clusters and metal-molecular complexes for 30 years. Numerous experiments in the …

Cluster size effects

J Jortner - Zeitschrift für Physik D Atoms, Molecules and Clusters, 1992 - Springer
In this paper we address some of the unique, novel and basic features of clusters, which
involve the physical and chemical consequences of their large surface/volume ratio and the …

Density functional theory study of palladium cluster adsorption on a graphene support

R Hussain, M Saeed, MY Mehboob, SU Khan… - RSC …, 2020 - pubs.rsc.org
The geometric, thermodynamic and electronic properties of Pd–graphene nanocomposites
are comprehensively studied through quantum mechanical methods. Geometries of these …

Discovering the fullerenes

RE Smalley - Reviews of Modern Physics, 1997 - APS
It is a thrill for me to be here today and to be the first of three speakers discussing the
wonders of the fullerenes, an infinite new class of carbon molecules. My colleagues in this …

Photoelectron spectroscopy of size‐selected transition metal clusters: Fen, n=3–24

LS Wang, HS Cheng, J Fan - The Journal of chemical physics, 1995 - pubs.aip.org
A higher resolution magnetic bottle photoelectron spectrometer for the study of the electronic
structure of size‐selected metal clusters is presented. The initial study on Fe− n (n= 3–24) is …

Chemical reactivity of size-selected supported clusters: An experimental setup

U Heiz, F Vanolli, L Trento… - Review of Scientific …, 1997 - pubs.aip.org
We describe an experimental setup for the investigation of the chemical reactivity of size-
selected, supported clusters. The clusters are generated by a high frequency laser …