Crazing and yielding in glassy polymers of high molecular weight

M Razavi, S Cheng, D Huang, S Zhang, SQ Wang - Polymer, 2020 - Elsevier
This feature article presents many experimental results in order to explain and advance our
understanding on crazing during tensile deformation of glassy polymers. Ample data are …

The Microscopic Structure–Property Relationship of Metal–Organic Polyhedron Nanocomposites

M Zhang, Y Lai, M Li, T Hong, W Wang… - Angewandte …, 2019 - Wiley Online Library
Monodispersed hairy nanocomposites with typical 2 nm (isophthalic acid) 24Cu24 metal–
organic polyhedra (MOP) as a core protected by 24 polymer chains with controlled narrow …

Extensional stress-induced orientation and crystallization can regulate the balance of toughness and stiffness of polylactide films: interplay of oriented amorphous …

XR Gao, Y Li, HD Huang, JZ Xu, L Xu, X Ji… - …, 2019 - ACS Publications
Polylactide (PLA) films with an excellent balance of toughness and stiffness were realized by
extensional stress efficiently. For the relatively low extensional stress, gauche–gauche …

Mechanochemically responsive polymer enables shockwave visualization

PJ Centellas, KD Mehringer, AL Bowman… - Nature …, 2024 - nature.com
Understanding the physical and chemical response of materials to impulsive deformation is
crucial for applications ranging from soft robotic locomotion to space exploration to …

Coupling effect of mechanical and thermal rejuvenation for polystyrene: toward high performance of stiffness, ductility, and transparency

Y Zeng, YT Xu, J Zhang, L Xu, X Ji, H Lin… - …, 2021 - ACS Publications
The challenge of hitherto elaborating a workable approach to overcome the conflicts
between stiffness, ductility, and transparency of polystyrene (PS) still remains among …

Building a phenomenological chain-level understanding of mechanics of semicrystalline polymers: 2. Conceptual

SQ Wang, T Smith, C Gupta, AY Siavoshani - Polymer, 2023 - Elsevier
To rationalize the comprehensive phenomenology in Paper 1 (this volume, p. 125878), we
present a qualitative description for the mechanical behavior of semicrystalline polymers …

Glassy gels toughened by solvent

M Wang, X Xiao, S Siddika, M Shamsi, E Frey, W Qian… - Nature, 2024 - nature.com
Glassy polymers are generally stiff and strong yet have limited extensibility. By swelling with
solvent, glassy polymers can become gels that are soft and weak yet have enhanced …

Thickness-dependent mechanical failure in thin films of glassy polymer bidisperse blends

T Zhang, RA Riggleman - Macromolecules, 2021 - ACS Publications
Although many studies have analyzed the various properties of glassy polymer thin films, the
failure mode and nonlinear mechanical response have only recently received attention. Due …

Polymer Thin Film Necking: Ductility from Entanglements and Plane Stress Condition

S Zhang, Z Cao, X Gu, T Ge - Macromolecules, 2024 - ACS Publications
The ductility of polymer thin films is critical to many applications such as organic electronics
and separation membranes. Large-scale molecular simulations are performed to reproduce …

Nonlinear stress relaxation behavior of ductile polymer glasses from large extension and compression

J Liu, P Lin, X Li, SQ Wang - Polymer, 2015 - Elsevier
We study nonlinear stress relaxation behavior of several polymer glasses during ductile
large deformation of either extension or compression over a wide range of deformation rate …