Single‐site heterogeneous catalysts

JM Thomas, R Raja, DW Lewis - … Chemie International Edition, 2005 - Wiley Online Library
Intellectually, the advantages that flow from the availability of single‐site heterogeneous
catalysts (SSHC) are many. They facilitate the determination of the kinetics and mechanism …

Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalysts

P McMorn, GJ Hutchings - Chemical Society Reviews, 2004 - pubs.rsc.org
Enantioselective formation of C–H, C–C, C–O and C–N bonds has been extensively studied
using homogeneous asymmetric catalysts for many years. However, these catalysts have yet …

Enhanced catalysis based on the surface environment of the silica-supported metal complex

K Motokura, S Ding, K Usui, Y Kong - ACS Catalysis, 2021 - ACS Publications
Silica-supported metal complex catalysts have been developed and used for organic
transformations. The surface environment around the supported metal complex enhances …

Hydrophilic ligands and their application in aqueous-phase metal-catalyzed reactions

KH Shaughnessy - Chemical reviews, 2009 - ACS Publications
Water is truly ubiquitous. Approximately 80% of the earth's surface is covered by water,
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …

Supported chiral catalysts on inorganic materials

CE Song, S Lee - Chemical Reviews, 2002 - ACS Publications
For economic, environmental, and social reasons, the trend toward the application of
optically pure compounds is undoubtedly increasing. Among the various methods to …

Noncovalent immobilization of enantioselective catalysts

JM Fraile, JI Garcia, JA Mayoral - Chemical reviews, 2009 - ACS Publications
Among the different methods to obtain enantiomerically pure compounds, namely,
resolution, diastereomeric synthesis, and enantioselective catalysis, the use of chiral …

New directions in supramolecular transition metal catalysis

MJ Wilkinson, PWNM van Leeuwen… - Organic & Biomolecular …, 2005 - pubs.rsc.org
Supramolecular chemistry has grown into a major scientific field over the last thirty years and
has fueled numerous developments at the interfaces with biology and physics, clearly …

Development of robust heterogeneous chiral rhodium catalysts utilizing acid–base and electrostatic interactions for efficient continuous-flow asymmetric …

Y Saito, S Kobayashi - Journal of the American Chemical Society, 2020 - ACS Publications
Heterogeneous chiral Rh catalysts based on acid–base and electrostatic interactions have
been developed. The robust catalysts demonstrate high activity and selectivity in the …

Catalytic self‐assembled monolayers on Au nanoparticles: The source of catalysis of a transphosphorylation reaction

G Zaupa, C Mora, R Bonomi, LJ Prins… - … –A European Journal, 2011 - Wiley Online Library
The catalytic activity of a series of Au monolayer protected colloids (Au MPCs) containing
different ratios of the catalytic unit triazacyclononane⋅ ZnII (TACN⋅ ZnII) and an inert …

Heterogene Single‐Site‐Katalysatoren

JM Thomas, R Raja, DW Lewis - Angewandte Chemie, 2005 - Wiley Online Library
Abstract Die Vorteile heterogener Single‐Site‐Katalysatoren (single‐site heterogeneous
catalysts, SSHCs) sind vielfältig. Sie ermöglichen es–sowohl experimentell als auch mit …