Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

In this review, the advances made over the last 6 years in [4+ 1]-annulation reactions
involving sulfonium, sulfoxonium and ammonium ylides, as well as diazo compounds and …

A highly efficient and practical method for incorporation of the arylmethylpyridyl moiety into
diverse molecules has been developed. This method features the transition metal-free light …

An efficient radical transannulation reaction of pyridotriazoles with isothiocyanates and
xanthate esters was developed. This method features conversion of pyridotriazoles into two …

A dehydrogenative [3+ 2] annulation reaction of aniline derivatives and alkenes has been
developed via the ruthenium-electron catalytic systems for the synthesis of versatile …

An efficient and novel rhodium-catalyzed transannulation of N-sulfonyl-1, 2, 3-triazoles with
in situ generated o-quinone methides (o-QMs) from 2-hydroxybenzyl alcohols has been …

Over the past decade, α‐imino carbenoids generated via transition metal (such as rhodium,
nickel, copper, palladium, silver) catalyzed denitrogenative ring‐opening of N‐sulfonyl‐1, 2 …

Polycyclic indoline‐benzodiazepines can be accessed through the intermolecular reaction
of Tröger bases with N‐sulfonyl‐1, 2, 3‐triazoles. Under RhII catalysis, α‐imino carbenes are …

Cyclopropenes are highly strained three-membered carbocycles, which offer unique
reactivity in organic synthesis. Herein, Cp* CoIII-catalyzed ring-opening isomerization of …

Unprecedented palladium-catalyzed denitrogenative Suzuki and carbonylative Suzuki
coupling reactions of benzotriazoles with boronic acids have been realized, which afforded …