Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …

This review describes the effects of highly deformed porphyrin ring on the electronic
structures of iron (III) porphyrinates, which includes (i) the electron configurations in low-spin …

The electronic ground state of most known ferric heme proteins is either low-spin (S) 1/2) or
high-spin (S) 5/2). However, a small number of these proteins do not conform to this regime …

Oxo-and hydroxo-bridged diiron active centers are common structural motifs found in a
variety of proteins in biology. The highly versatile oxo/hydroxo-bridged dimetallic centers …

The mechanism of styrene polymerization by α‐diimine iron complexes correlates with the
metal spin state of the catalyst. Experimental and theoretical studies indicate that high‐spin …

A panel of iridium (III) porphyrin complexes containing axial N-heterocyclic carbene (NHC)
ligand (s) were synthesized and characterized. X-ray crystal structures of the bis-NHC …

BisFe (III) porphyrins bridged by a highly flexible ethane linker are reported in which the
bisporphyrin platform “opens” and “closes” its binding pockets leading to facile syn-anti …

The chemistry of oxo/hydroxo-bridged diheme centers, connected covalently through
bridges, has attracted much attention recently. Close approach of the two heme centers in …

We have reported here, for the first time, the parallel and perpendicular orientation
preferences of two planar and unhindered imidazoles as axial ligands (L) while coordinated …