[HTML][HTML] Macrocyclization reactions: the importance of conformational, configurational, and template-induced preorganization

V Marti-Centelles, MD Pandey, MI Burguete… - Chemical …, 2015 - ACS Publications
Macrocyclic structures are common synthetic targets in drug discovery,(1, 2) and therefore,
interest in their study is continuously increasing in this field.(3, 4) A classic example is …

Polymeric rotaxanes

A Harada, A Hashidzume, H Yamaguchi… - Chemical …, 2009 - ACS Publications
In the past three decades, chemistry has changed from focusing on a single molecule to
molecular assemblies. Through the discovery of macrocycles, the chemistry of molecular …

Dynamic combinatorial/covalent chemistry: a tool to read, generate and modulate the bioactivity of compounds and compound mixtures

A Herrmann - Chemical Society Reviews, 2014 - pubs.rsc.org
Reversible covalent bond formation under thermodynamic control adds reactivity to self-
assembled supramolecular systems, and is therefore an ideal tool to assess complexity of …

Schiff base and non-Schiff base macrocyclic ligands and complexes incorporating the pyridine moiety–The first 50 years

M Rezaeivala, H Keypour - Coordination Chemistry Reviews, 2014 - Elsevier
In this paper, there is an attempt to review the developments in the design and synthesis of
pyridine containing [1+ 1] and [2+ 2] macrocyclic Schiff base ligands, formed by …

Template-directed synthesis employing reversible imine bond formation

CD Meyer, CS Joiner, JF Stoddart - Chemical Society Reviews, 2007 - pubs.rsc.org
The imine bond–formed by the reversible condensation of an amine and an aldehyde–and
its applications as a dynamic covalent bond in the template-directed synthesis of molecular …

Photo-driven molecular devices

S Saha, JF Stoddart - Chemical Society Reviews, 2007 - pubs.rsc.org
In this critical review, we discuss switching of the light-powered bistable rotaxanes and
catenanes and highlight the practical applications of some of these systems. Photoactive …

Solvent-responsive reversible and controllable conversion between a polyimine membrane and an organic molecule cage

QH Zhu, GH Zhang, L Zhang, SL Wang… - Journal of the …, 2023 - ACS Publications
Adaptive bionic self-correcting behavior offers an attractive property for chemical systems.
Here, based on the dynamic feature of imine formation, we propose a solvent-responsive …

Mechanically interlocked molecular handcuffs

N Pearce, M Tarnowska, NJ Andersen… - Chemical …, 2022 - pubs.rsc.org
The field of mechanically interlocked molecules that employ a handcuff component are
reviewed. The variety of rotaxane and catenane structures that use the handcuff motif to …

Design and Assembly of Rotaxane‐Based Molecular Switches and Machines

W Yang, Y Li, H Liu, L Chi, Y Li - Small, 2012 - Wiley Online Library
Mechanically interlocked molecules, such as catenanes and rotaxanes, are at the heart of
the development of molecular machines chemistry. They are able to self‐organize, self …

pH-dependent assembly of supramolecular architectures from 0D to 2D networks

ST Wu, LS Long, RB Huang, LS Zheng - Crystal growth & design, 2007 - ACS Publications
Five Cu (II)/benzoate/4, 4 '-bipy complexes, namely,[Cu (H2O)(benzoate) 2 (4, 4 '-bipy)
2](benzoic acid) 2⊙(4, 4 '-bipy)(1),[Cu2 (H2O) 2 (benzoate) 4 (4, 4 '-bipy) 3]⊙(H2O) 9 …