Promising Catalytic Application by Pincer Metal Complexes: Recent Advances in Hydrogenation of Carbon‐Based Molecules

KK Manar, J Cheng, Y Yang, X Yang, P Ren - ChemCatChem, 2023 - Wiley Online Library
In the last two decades, pincer metal complexes have been highly utilized as catalysts for a
variety of organic transformations in both industrial and social applications. Owing to the …

Manganese (I)‐Catalyzed Chemoselective Transfer Hydrogenation of the C= C Bond in Conjugated Ketones at Room Temperature

DM Sharma, AB Shabade… - … –A European Journal, 2023 - Wiley Online Library
Chemoselective transfer hydrogenation of C= C bond in α, β‐unsaturated ketones is
demonstrated at room temperature employing a manganese (I) catalyst and half an …

Unraveling the Metal–Ligand Cooperativity in a Phosphine-Free Mn (II)-Catalyzed Transfer Hydrogenation of Nitriles to Primary Amines and Dehydrogenation of …

D Chowdhury, K Gupta, RK Gamidi, G Jindal… - ACS …, 2024 - ACS Publications
Selective synthesis of primary amines from nitriles is challenging in synthetic chemistry
owing to the possible en route formation of various amines and imines. Herein, we report a …

Catalytic Base‐Free Transfer Hydrogenation of Biomass Derived Furanic Aldehydes with Bioalcohols and PNP Pincer Complexes

R Padilla, Z Ni, D Mihrin, R Wugt Larsen… - …, 2023 - Wiley Online Library
The base‐free transfer hydrogenation of biomass derived furanic aldehydes with ruthenium
and iridium pincer complexes was studied using bio‐alcohols as the hydrogen source. The …

Well-Defined Robust Imidazole-Based Metal–Ligand Cooperative Ru(II)-para-Cymene for Transfer Hydrogenation of Furanic Aldehydes Using Renewable Alcohols

RD Patil, S Pratihar - ACS Sustainable Chemistry & Engineering, 2024 - ACS Publications
The present study addresses the challenges in catalytic transfer hydrogenation using
methanol/ethanol for converting biomass-derived furanic aldehydes to furfuryl alcohols. The …

Efficient and chemoselective imine synthesis catalyzed by a well-defined PN 3-manganese (ii) pincer system

SS Gholap, A Al Dakhil, P Chakraborty… - Chemical …, 2024 - pubs.rsc.org
The highly efficient reductive amination of aldehydes with ammonia (NH3) and hydrogen
(H2) to form secondary imines is described, as well as the dehydrogenative homocoupling …

[HTML][HTML] Transformation of Ambient CO2 in Air into Cyclic Carbonates Mediated by a Phosphorus-Nitrogen PN3-Pincer Iron Complex

L Yang, P Chakraborty, PK Das, D Zhang… - Green Synthesis and …, 2024 - Elsevier
The atom-economical reaction of carbon dioxide (CO 2) with epoxides possesses the
potential to utilize captured CO₂ for synthesizing useful chemicals. Among a wide range of …

Biowaste carbon supported manganese nanoparticles as an active catalyst for the selective hydrogenation of bio-based aldehydes

N Sarki, A Narani, G Naik, D Tripathi, SL Jain, K Natte - Catalysis Today, 2023 - Elsevier
Hydrogenation of aldehydes with heterogeneous manganese catalysts is an appealing
approach for producing alcohols. In this paper, we report a novel and robust MnO/PN-800 …