Exploration of glassy state in Prussian blue analogues

N Ma, R Ohtani, HM Le, SS Sørensen… - Nature …, 2022 - nature.com
Prussian blue analogues (PBAs) are archetypes of microporous coordination
polymers/metal–organic frameworks whose versatile composition allows for diverse …

Dual redox-active copper hexacyanoferrate nanosheets as cathode materials for advanced sodium-ion batteries

Y Xu, J Wan, L Huang, J Xu, M Ou, Y Liu, X Sun… - Energy Storage …, 2020 - Elsevier
Abstract Prussian Blue Analogs (PBAs) such as copper hexacyanoferrate (CuHCF) are
traditional intercalation cathodes for rechargeable Na-ion batteries. However, the …

Unlocking Prussian Blue Analogues Inert‐Site to Achieve High‐Capacity Ammonium Storage

Y Shen, J Zou, H Lan, Y Ding, Z Liang… - Advanced Functional …, 2024 - Wiley Online Library
Aqueous ammonium‐ion batteries (AIBs) are considered a promising alternative for large‐
scale energy storage due to their cost‐effectiveness and high safety. Prussian blue …

Tracking Sub-Nano-Scale Structural Evolution in Zeolite Synthesis by In Situ High-Energy X-ray Total Scattering Measurement with Pair Distribution Function Analysis

A Minami, P Hu, Y Sada, H Yamada… - Journal of the …, 2022 - ACS Publications
The crystallization mechanism of zeolites remains unclarified to date because of lack of
effective techniques in characterizing the local structures of amorphous precursors under …

Uncovering the Interplay of Competing Distortions in the Prussian Blue Analogue K2Cu[Fe(CN)6]

J Cattermull, K Sada, K Hurlbutt, SJ Cassidy… - Chemistry of …, 2022 - ACS Publications
We report the synthesis, crystal structure, thermal response, and electrochemical behavior of
the Prussian blue analogue (PBA) K2Cu [Fe (CN) 6]. From a structural perspective, this is …

Probing the influence of defects, hydration, and composition on Prussian Blue Analogues with pressure

HLB Bostrom, IE Collings, D Daisenberger… - Journal of the …, 2021 - ACS Publications
The vast compositional space of Prussian blue analogues (PBAs), formula A x M [M′(CN)
6] y· n H2O, allows for a diverse range of functionality. Yet, the interplay between …

Radiation effects, zero thermal expansion, and pressure-induced phase transition in CsMnCo (CN) 6

HLB Boström, AB Cairns, M Chen… - Physical Chemistry …, 2022 - pubs.rsc.org
The Prussian blue analogue CsMnCo (CN) 6 is studied using powder X-ray and neutron
diffraction under variable temperature, pressure, and X-ray exposure. It retains cubic F3m …

Catalytic adventures in space and time using high energy X-rays

MA Newton, M Di Michiel, D Ferri… - Catalysis Surveys from …, 2014 - Springer
Very high energy X-rays (ca.> 40 keV) have long offered great promise in providing great
insight into the inner workings of catalysts; insights that may complement the battery of …

Loading and thermal behaviour of ZIF-8 metal–organic framework-inorganic glass composites

AM Chester, C Castillo-Blas, R Sajzew… - Dalton …, 2024 - pubs.rsc.org
Here we describe the synthesis of a compositional series of metal–organic framework
crystalline-inorganic glass composites (MOF-CIGCs) containing ZIF-8 and an inorganic …

High energy surface x-ray diffraction applied to model catalyst surfaces at work

U Hejral, M Shipilin, J Gustafson, A Stierle… - Journal of Physics …, 2020 - iopscience.iop.org
Catalysts are materials that accelerate the rate of a desired chemical reaction. As such, they
constitute an integral part in many applications ranging from the production of fine chemicals …