Polyoxometalate-based frameworks as chemical nanoreactors: in situ synthesis of active silver nanoparticles in confined spaces
HM Zeng, XJ Wang, ZG Jiang, CH Zhan - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
The synthesis of metal catalysts confined in porous materials is still a great challenge. Here,
a framework sustained by bulky rigid polyoxometalate (POM) blocks [Mo36O112 (H2O) 16] …
a framework sustained by bulky rigid polyoxometalate (POM) blocks [Mo36O112 (H2O) 16] …
Nanoblackberries of {W72Fe33} and {Mo72Fe30}: Electrocatalytic Water Reduction
The reversible self-assembly of a {Mo72Fe30} cluster into nanoblackberries in a dilute
solution of the relevant crystalline compound [Mo72Fe30O252 (CH3COO) 12 {Mo2O7 …
solution of the relevant crystalline compound [Mo72Fe30O252 (CH3COO) 12 {Mo2O7 …
A New Aryl Sulfonium Polyoxomolybate with One-Electron Reduced Keggin Cluster: Crystal Structure, Hirshfeld Analysis, and Photochromic Activity
A Kar - Journal of Molecular Structure, 2022 - Elsevier
Herein, we report the mechanochemical synthesis of a new aryl sulfonium polyoxometalate
(ASPOM),(FPDS) 3 [PMo 12 O 40](FPMA)(FPDS=(4-formylphenyl) dimethylsulfonium)) and …
(ASPOM),(FPDS) 3 [PMo 12 O 40](FPMA)(FPDS=(4-formylphenyl) dimethylsulfonium)) and …
Ultrasensitive photochromism and impedance dual response to weak visible light by solvated Pb (II) modified polyoxomolybdate
J Zhang, X Wang, G Wang, Y Feng, C Zhang… - Chinese Chemical …, 2023 - Elsevier
Polyoxometalates (POMs) are important inorganic photochromic materials to be potentially
applied in photo-induced switch, energy storage, and even the detection of light. However …
applied in photo-induced switch, energy storage, and even the detection of light. However …
Advances in gigantic polyoxomolybdate chemistry
Since 1996 when Müller et al. determined the first giant Molybdenum Blue (MB) wheel {Mo
154} and revealed the 200-year-old mystery, many hundreds of compounds of this type and …
154} and revealed the 200-year-old mystery, many hundreds of compounds of this type and …
Visible‐Light Photochromism of Polyoxometallate H4PMo11VO40 Composite Film Based on Polyvinylpyrrolidone with a Fast Response
Z Wang, L Ai, M Liu, Z Wang - ChemistrySelect, 2024 - Wiley Online Library
The visible‐light photochromic composite films with a fast response were prepared by
entrapping H4PMo11VO40 into polyvinylpyrrolidone (PVP) networks. PMo11V/PVP …
entrapping H4PMo11VO40 into polyvinylpyrrolidone (PVP) networks. PMo11V/PVP …