Understanding the rules of life is one of the most important scientific endeavours and has
revolutionised both biology and biotechnology. Remarkable advances in observation …

Hydrogen atom transfer (HAT) is a salient feature of many enzymatic C–H cleavage
mechanisms. In systems where kinetic isolation of HAT is achieved, selective labeling of …

Proton-coupled electron transfer (PCET) reactions are fundamental to energy transformation
reactions in natural and artificial systems and are increasingly recognized in areas such as …

One of the most important topics in molecular biology is the genetic stability of DNA. One
threat to this stability is proton transfer along the hydrogen bonds of DNA that could lead to …

Proton-coupled energy transfer in molecular triads | Science news careers commentary
Journals Science Science brought to you byGoogle Indexer Log in science science …

This account article focuses on deuterium kinetic isotope effects (KIEs) used as criterions to
elucidate redox mechanisms including proton‐, hydrogen‐and hydride‐transfer reactions …

The Born–Oppenheimer approximation, which assumes that the electrons respond
instantaneously to the motion of the nuclei, breaks down for a wide range of chemical and …

The physical basis for enzymatic rate accelerations is a subject of great fundamental interest
and of direct relevance to areas that include the de novo design of green catalysts and the …

We simulate two recent matrix‐isolation experiments at cryogenic temperatures, in which a
nitrene undergoes spin crossover from its triplet state to a singlet state via quantum …

The photoacid dynamics of fluorescent proteins include both electronic excited-and ground-
state mechanisms of proton transfer. The associated characteristic timescales of these …