Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Control of charge transfer in donor/acceptor metal–organic frameworks

H Miyasaka - Accounts of chemical research, 2013 - ACS Publications
Charge transfer (CT) of D0A0↔ Dδ+ Aδ− not only involves an electron transfer from D to A,
but also generates a new spin set of S= 1/2 spins with an exchange interaction. Therefore …

Guest-induced emergent properties in metal–organic frameworks

MD Allendorf, ME Foster, F Leonard… - The journal of …, 2015 - ACS Publications
Metal–organic frameworks (MOFs) are crystalline nanoporous materials comprised of
organic electron donors linked to metal ions by strong coordination bonds. Applications such …

Inverted metal–organic frameworks: solid-state hosts with modular functionality

GS Papaefstathiou, LR MacGillivray - Coordination chemistry reviews, 2003 - Elsevier
Metal–organic frameworks (MOFs) are crystalline inorganic–organic hybrid materials that
consist of metal ions and organic molecules connected in space to produce an infinite one …

Controlling charge separation in a novel donor–acceptor metal–organic framework via redox modulation

CF Leong, B Chan, TB Faust, DM D'Alessandro - Chemical Science, 2014 - pubs.rsc.org
Charge transfer metal–organic frameworks represent a versatile class of multifunctional
materials that offer an unprecedented combination of physical properties. The framework …

From molecules to materials: Molecular paddle-wheel synthons of macromolecules, cage compounds and metal–organic frameworks

M Köberl, M Cokoja, WA Herrmann, FE Kuehn - Dalton Transactions, 2011 - pubs.rsc.org
Metal–organic frameworks (MOF) are becoming a more and more important class of
functional materials. Yet, very often, the synthesis of MOFs is not easy to control and requires …

Intrinsically conducting metal–organic frameworks

CF Leong, PM Usov, DM D'Alessandro - MRS Bulletin, 2016 - cambridge.org
The development of metal–organic frameworks (MOFs) as microporous electronic
conductors is an exciting research frontier that has the potential to revolutionize a wide …

Recent developments in the synthesis and properties of diruthenium tetracarboxylates

MAS Aquino - Coordination Chemistry Reviews, 2004 - Elsevier
The chemistry of diruthenium tetracarboxylates has grown substantially since our initial
review in 1998. This update of the literature through 2003 covers the versatile synthetic …

Magnetic interactions in one-, two-, and three-dimensional assemblies of dinuclear ruthenium carboxylates

M Mikuriya, D Yoshioka, M Handa - Coordination Chemistry Reviews, 2006 - Elsevier
Dinuclear ruthenium complexes which have metal–metal bonds within a paddlewheel
dinuclear core are currently recognized, because of their unique magnetic properties, as …

Mixed valency as a strategy for achieving charge delocalization in semiconducting and conducting framework materials

R Murase, CF Leong, DM D'Alessandro - Inorganic Chemistry, 2017 - ACS Publications
The fundamentally important phenomenon of mixed valency has been discussed in detail
over the past 50 years, predominantly in the context of dinuclear complexes, which are used …