Redox-active ligands: Recent advances towards their incorporation into coordination polymers and metal-organic frameworks

B Ding, MB Solomon, CF Leong… - Coordination Chemistry …, 2021 - Elsevier
Over the past three decades, the field of coordination polymers (CPs) and metal–organic
frameworks (MOFs) has developed rapidly due to the potential applications of these …

Recent Developments in the Syntheses of Aluminum Complexes Based on Redox-Active Ligands

PS Gahlaut, K Yadav, D Gautam, B Jana - Journal of Organometallic …, 2022 - Elsevier
Applications of aluminum as a catalyst for organic/inorganic transformation reactions are
ideal because of its easy availability, inexpensiveness, and non-toxicity. However …

Syntheses of Dianionic α-Iminopyridine Rare-Earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes

X Zhang, S Zhou, X Fang, L Zhang, G Tao… - Inorganic …, 2020 - ACS Publications
Reactions of [(Me3Si) 2N] 3RE (μ-Cl) Li (THF) 3 with aminomethylene-substituted pyridine 2-
[O (CH2CH2) 2NCH2CH2NCH2] C5H4N (1) gave the dianionic α-iminopyridine rare-earth …

Syntheses of rare-earth metal alkyl complexes bearing a dianionic α-iminopyridyl ligand and their catalytic activities toward polymerization of 2-vinylpyridine

X Zhang, S Zhou, D Wang, L Zhang, Y Wei… - …, 2021 - ACS Publications
The rare-earth metal alkyl complexes bearing a dianionic α-iminopyridyl ligand {μ-η2: σ1: κ1:
κ1-2-[O (CH2CH2) 2NCH2CH2NCH] C5H4N} 2RE2 (CH2SiMe3) 2 (THF) n (n= 2, RE= Gd …

Aluminum Dihalide Complexes Based on the 1, 2-bis [(2, 6-dibenzhydryl-4-methylphenyl) imino] Acenaphthene Ligand

MV Moskalev, NL Bazyakina, EV Baranov… - Journal of Structural …, 2024 - Springer
Abstract Reduction of ArBIG-bian (ArBIG-bian= 1, 2-bis [(2, 6-dibenzhydryl-4-methylphenyl)
imino] acenaphthene) by an excess of metal aluminum in the presence of AlCl3, AlBr3 or …

Versatile Electronic and Structural Properties of Ruthenium-Mediated 1,4-Diaza-1,3-butadiene Ligands: A Review

AS Roy - Russian Journal of Coordination Chemistry, 2024 - Springer
Ruthenium α-diimine complexes are widely known for their unique low-lying excited states
and potent light absorption capabilities in the visible and NIR regions. A few specially …

Unusually Strong Long-range Electronic Coupling Across Redox-Active Bridges in M3+/M4+ Mixed-Valence Complexes of Group 4 Congeners

CS Bell, NJ DeYonker, CE Moore, KM Clark - 2021 - chemrxiv.org
Homobimetallic complexes of Group 4 metals, supported by the redox-active tetrakis (imino)
pyracene (TIP) ligand were synthesized and isolated. The formation of these complexes …

Synthesis and Characterization of (pyNO)2GaCl: A Redox-Active Gallium Complex

JM Kirsh, AJ Woodside, BC Manor, PJ Carroll… - Inorganics, 2018 - mdpi.com
We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide
ligands. The (pyNO−) 2GaCl complex was prepared in 85% yield via a salt metathesis route …

ДИГАЛОГЕНИДЫЕ КОМПЛЕКСЫ АЛЮМИНИЯ НА ОСНОВЕ 1, 2-БИС [(2, 6-ДИБЕНЗГИДРИЛ-4-МЕТИЛФЕНИЛ) ИМИНО] АЦЕНОФТЕНОВОГО ЛИГАНДА

МВ МОСКАЛЕВ, НЛ БАЗЯКИНА… - ЖУРНАЛ …, 2024 - elibrary.ru
Восстановление Ar BIG-bian (Ar BIG-bian= 1, 2-бис [(2, 6-дибензгидрил-4-метилфенил)
имино] аценафтен) избытком металлического алюминия в присутствии AlCl 3, AlBr 3 …

A Ligand Protonation Series in Aluminum (III) Complexes of Tridentate Bis (enol) amine Ligand

NA Phan, JC Fettinger, LA Berben - Organometallics, 2018 - ACS Publications
A series of aluminum (III) complexes supported by the tridentate bis (enol) amine ligand
(ONO, 1, 1′-azanediylbis (3, 3-dimethylbutan-2-one)) in two protonation states have been …