In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs
have been made by rational design and meticulous selection of chiral ligands. This review …

A rhodium (III)-catalyzed enantioselective C–H activation/annulation process is disclosed.
With a catalyst derived from a chiral CpRh (III) complex and a chiral acid, the direct …

Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …

Enantiopure [6] helicene containing an embedded seven‐membered ring and carbo [7]
helicene (> 99% ee) with opposite helicity were simultaneously and quantitatively (> 99%) …

Despite the considerable potential applications for helically chiral molecules across various
sectors, their catalytic asymmetric synthesis remains nascent and has seen very limited …

We report a unique category of π‐extended diaza [7] helicenes with double negative
curvatures. This is achieved by two‐fold regioselective heptagonal cyclization of the …

We report the quantitative, chemoselective, and diastereospecific formation of the defect‐
free C‐shaped single and S‐and M‐shaped consecutively fused double‐and triple …

A chiral phosphathiahelicene scaffold displaying a phosphole and a thiophene unit as the
terminal rings of the helical sequence has been synthesized and characterized by …

We report the helicoselective and convergent construction of indolohelicenoids with
excellent efficiency and stereocontrol. This reaction proceeds through a chiral‐phosphoric …