1.1. Inspired by Nature In many enzymes, such as ureases (Figure 1), two or more metal
centers are poised in close proximity to activate both electrophilic and nucleophilic …

Pentafulvenes are a unique class of compounds that originally attracted attention due to
their propensity to display nonbenzenoid aromaticity. Subsequently, they were recognized …

Organometallic chemistry has provided the foundation for the development of a wide range
of new olefin polymerization catalysts over the last two to three decades. The unraveling of …

A series of 0− 3 metal oxide− polyolefin nanocomposites are synthesized via in situ olefin
polymerization, using the following single-site metallocene catalysts: C 2-symmetric dichloro …

A number of transition metal catalysts including early and late transition metals have been
investigated for olefin polymerization and copolymerization. Progress of the field in this …

Isotactic polypropylene (iPP) is a thermoplastic material of vast importance. The ever-
increasing demand for it is derived from its useful physical properties and the availability of …

We have investigated the olefin polymerization mechanism of hafnium catalysts supported
by a pyridyl− amide ligand with an ortho-metalated naphthyl group. Ethylene− α-olefin …

The 0− 3 metal oxide− isotactic polypropylene nanocomposites are synthesized via in situ
propylene polymerization using the C 2-symmetric metallocene catalyst dichloro [rac …

Influence of solvent on cyclic polynorbornene tacticity - Chemical Communications (RSC
Publishing) DOI:10.1039/D3CC04167K Royal Society of Chemistry View PDF VersionPrevious …

This contribution describes the homopolymerization of styrene and the copolymerization of
ethylene and styrenic comonomers mediated by the single-site bimetallic “constrained …