Alkenylation of arenes and heteroarenes with alkynes

VP Boyarskiy, DS Ryabukhin, NA Bokach… - Chemical …, 2016 - ACS Publications
This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …

Recent applications of radical cascade reaction in the synthesis of functionalized 1-indenones

Y Zhang, K Sun, Q Lv, X Chen, L Qu, B Yu - Chinese Chemical Letters, 2019 - Elsevier
Indenones are important scaffolds in natural products, biologically active molecules as well
as functional materials. Recently, radical cascade cyclization has emerged as an efficient …

Fused Indacene Dimers

T Xu, X Hou, Y Han, H Wei, Z Li, C Chi - Angewandte Chemie, 2023 - Wiley Online Library
Polycyclic hydrocarbons consisting of two or more directly fused antiaromatic subunits are
rare due to their high reactivity. However, it is important to understand how the interactions …

Copper-Catalyzed Annulation–Trifluoromethyl Functionalization of Enynones

JY Wang, S Zhang, Y Tang, S Yan, G Li - Organic Letters, 2023 - ACS Publications
The Cu (I)-catalyzed annulation–halotrifluoromethylation and cyanotrifluoromethylation of
enynones have been established, enabling multibond formations of the synthesis of …

Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of β-alkynyl propenones

ZJ Shen, YN Wu, CL He, L He, WJ Hao… - Chemical …, 2018 - pubs.rsc.org
New radical-triggered multi-component cyclizations of β-alkynyl propenones have been
developed, leading to 50 examples of sulfonated 1-indenones with generally good yields …

Copper-catalyzed radical cascade cyclization to access 3-sulfonated indenones with the AIE phenomenon

K Sun, XL Chen, SJ Li, DH Wei, XC Liu… - The Journal of …, 2018 - ACS Publications
An efficient copper-catalyzed radical cascade cyclization strategy was developed, by which
a wide variety of 3-sulfonyl substituted indenones were prepared in one pot via reaction of 2 …

MeOTf- and TBD-Mediated Carbonylation of ortho-Arylanilines with CO2 Leading to Phenanthridinones

S Wang, P Shao, G Du, C Xi - The Journal of organic chemistry, 2016 - ACS Publications
Carbonylation of o-arylanilines utilizing CO2 as a carbonyl source for the synthesis of
important phenanthridinones with a free (NH)-lactam motif has been described under metal …

Palladium/Norbornene‐Catalyzed Indenone Synthesis from Simple Aryl Iodides: Concise Syntheses of Pauciflorol F and Acredinone A

F Liu, Z Dong, J Wang, G Dong - … Chemie International Edition, 2019 - Wiley Online Library
To show the synthetic utility of palladium/norbornene (Pd/NBE) cooperative catalysis, here
we report concise syntheses of indenone‐based natural products, pauciflorol F and …

Sustainable mechanosynthesis of biologically active molecules

O Bento, F Luttringer, T Mohy El Dine… - European Journal of …, 2022 - Wiley Online Library
Synthetic mechanochemistry, the use of mechanical force produced by milling, grinding or
extruding, as an activation technique, provides access to chemical entities of all kinds. This …

Synthesis of indanones and spiroindanones by diastereoselective annulation based on a hydrogen autotransfer strategy

Y Chen, Z Ding, Y Wang, W Liu… - Angewandte Chemie …, 2021 - Wiley Online Library
An unprecedented nickel‐catalyzed domino reductive cyclization of alkynes and o‐
bromoaryl aldehydes is described. The reaction features broad substrate scope and is …