Over the past few decades, the advent of C–H activation has led to a rethink among
chemists about the synthetic strategies employed for multi-step transformations. Indeed …

Isocoumarins are lactonic natural products abundant in microbes and higher plants. These
are considered an amazing scaffold consecrated with more or less all types of …

Organic transformations catalyzed by cyclopentadienyl complexes of Group 9 metals (cobalt,
rhodium and iridium) are the key steps of the total synthesis of various natural products …

The dual catalytic strategy provides an effective and convenient solution for the synthesis of
complex or hard-integrated frameworks. The cooperation of NHCs and other catalysts has …

This review aims to summarize the recent advances in the field of Cp* MIII (Co, Rh, Ir)‐
catalyzed C–H activation followed by subsequent intramolecular reaction. This approach …

A transition metal‐free N‐arylation of primary and secondary amines with diaryliodonium
salts is presented. Both acyclic and cyclic amines are well tolerated, providing a large set of …

Efficient protocols for the synthesis of triphenylcyclopentadienyl rhodium halides [(1, 2, 4-
C5Ph3H2) RhX2] 2 (1a, b: X= Cl, I) starting from 1, 2, 4-triphenylcyclopentadiene or the …

A one‐pot sequential N‐heterocyclic carbene–rhodium (NHC‐Rh) catalysis is described,
demonstrating the compatibility of NHC and Rh catalysts. N‐Heterocyclic carbene‐catalyzed …

This work demonstrates the influence of the catalyst and alkyne nature on the
regioselectivity of rhodium-catalyzed annulation of alkoxy-substituted benzoic acids (such as …

It has been established that a cationic rhodium (I)/BIPHEP complex is able to catalyze the
unprecedented intermolecular cross-cyclotrimerization of nonactivated terminal and internal …