Plasmon-induced hot-hole generation and extraction at nano-heterointerfaces for photocatalysis

M Ahlawat, D Mittal, V Govind Rao - Communications Materials, 2021 - nature.com
Localized surface plasmon resonance excitation presents tremendous opportunities for light-
harvesting in the field of photocatalysis. Notably, the use of plasmon-generated hot carriers …

From optical to chemical hot spots in plasmonics

J Gargiulo, R Berté, Y Li, SA Maier… - Accounts of chemical …, 2019 - ACS Publications
Conspectus In recent years, the possibility to induce chemical transformations by using
tunable plasmonic modes has opened the question of whether we can control or create …

Determining plasmonic hot-carrier energy distributions via single-molecule transport measurements

H Reddy, K Wang, Z Kudyshev, L Zhu, S Yan, A Vezzoli… - Science, 2020 - science.org
Hot carriers in plasmonic nanostructures, generated via plasmon decay, play key roles in
applications such as photocatalysis and in photodetectors that circumvent bandgap …

Challenges in plasmonic catalysis

E Cortés, LV Besteiro, A Alabastri, A Baldi… - ACS …, 2020 - ACS Publications
The use of nanoplasmonics to control light and heat close to the thermodynamic limit
enables exciting opportunities in the field of plasmonic catalysis. The decay of plasmonic …

The fast and the furious: Ultrafast hot electrons in plasmonic metastructures. Size and structure matter

LV Besteiro, P Yu, Z Wang, AW Holleitner, GV Hartland… - Nano Today, 2019 - Elsevier
This review focuses on the generation of energetic (hot) electrons in plasmonic
metastructures and nanomaterials, and their characterization through time-resolved …

Tracking ultrafast hot-electron diffusion in space and time by ultrafast thermomodulation microscopy

A Block, M Liebel, R Yu, M Spector, Y Sivan… - Science …, 2019 - science.org
The ultrafast response of metals to light is governed by intriguing nonequilibrium dynamics
involving the interplay of excited electrons and phonons. The coupling between them leads …

Intrinsic optical properties and emerging applications of gold nanostructures

Z Guo, G Yu, Z Zhang, Y Han, G Guan… - Advanced …, 2023 - Wiley Online Library
The collective oscillation of free electrons at the nanoscale surface of gold nanostructures is
closely modulated by tuning the size, shape/morphology, phase, composition, hybridization …

Electronic structure of the plasmons in metal nanocrystals: fundamental limitations for the energy efficiency of hot electron generation

L Chang, LV Besteiro, J Sun, EY Santiago… - ACS Energy …, 2019 - ACS Publications
This Review discusses the electronic structure of plasmonic resonances in metal
nanostructures, clarifying existing misconceptions on the topic. Here we underscore the key …

Efficiency of hot-electron generation in plasmonic nanocrystals with complex shapes: surface-induced scattering, hot spots, and interband transitions

EY Santiago, LV Besteiro, XT Kong… - Acs …, 2020 - ACS Publications
The generation of hot electrons is an intrinsic property of all plasmonic nanocrystals under
illumination. However, the number of such excited electrons will strongly depend on the …

Ultrafast hot electron dynamics in plasmonic nanostructures: experiments, modelling, design

A Schirato, M Maiuri, G Cerullo, G Della Valle - Nanophotonics, 2023 - degruyter.com
Metallic nanostructures exhibit localized surface plasmons (LSPs), which offer
unprecedented opportunities for advanced photonic materials and devices. Following …