Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

Abstract The 1, 2-arylheteroaryl ethane motif stands as a privileged scaffold with promising
implications in drug discovery. Conventional de novo syntheses of these molecules have …

Contemporary methods for synthesizing thioesters often necessitate expensive catalysts and
harsh conditions, making their synthesis from chemical feedstocks challenging. Herein, we …

Thioesters are important in synthesis, materials science, and biology, and their preparation
traditionally relies on the use of disagreeable thiols. Here, we report a thiol‐free protocol that …

Carboxylic acids and thiols are basic chemical compounds with diverse utility and
widespread reactivity. However, the direct conversion of unprotected acids to thiols is …

Herein, a practical and effective synthesis of thioesters from readily available carboxylic
acids and odorless disulfides was developed under photocatalytic conditions. This approach …

The selective coupling of two different radicals is a long‐standing challenge due to the
process occurring statistically. Generally, the cross‐coupling selectivity is achieved by the …

Acylation stands as a fundamental process in both biological pathways and synthetic
chemical reactions, with acylated saccharides and their derivatives holding diverse …

Herein, we unveiled a regio-and diastereoselective synthesis of cyclobutylated
phenothiazines, a unique class of structural congeners of phenothiazines via visible-light …

An efficient organophosphorus-catalyzed thiocarbonylation reaction of disulfides with
carboxylic acids under air conditions was described. Various functional groups on carboxylic …