Enantioenriched helicenes and helicenoids containing main-group elements (B, Si, N, P)

K Dhbaibi, L Favereau, J Crassous - Chemical reviews, 2019 - ACS Publications
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Advancements in organic small molecule hole-transporting materials for perovskite solar cells: past and future

P Murugan, T Hu, X Hu, Y Chen - Journal of Materials Chemistry A, 2022 - pubs.rsc.org
This review article discusses the current designs and synthetic procedures for organic small
molecules as hole-transporting materials (HTMs) with a focus on their structure–property …

Sequential multiple borylation toward an ultrapure green thermally activated delayed fluorescence material

S Uemura, S Oda, M Hayakawa… - Journal of the …, 2022 - ACS Publications
Multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters have
emerged as an important component of organic light-emitting diodes (OLEDs) because of …

B, N-embedded double hetero [7] helicenes with strong chiroptical responses in the visible light region

JK Li, XY Chen, YL Guo, XC Wang… - Journal of the …, 2021 - ACS Publications
The development of helicene molecules with significant chiroptical responses covering a
broad range of the visible spectrum is highly desirable for chiral optoelectronic applications; …

One-shot synthesis of expanded heterohelicene exhibiting narrowband thermally activated delayed fluorescence

S Oda, B Kawakami, Y Yamasaki… - Journal of the …, 2021 - ACS Publications
An expanded heterohelicene consisting of three BN2-embedded [4] helicene subunits (V-
DABNA-Mes) has been synthesized by one-shot triple borylation. The key to success is the …

Solution‐processable pure green thermally activated delayed fluorescence emitter based on the multiple resonance effect

N Ikeda, S Oda, R Matsumoto, M Yoshioka… - Advanced …, 2020 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) materials based on the multiple
resonance (MR) effect are applied in organic light‐emitting diodes (OLEDs), combining high …

Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems

M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …

π-Extended perylene diimide double-heterohelicenes as ambipolar organic semiconductors for broadband circularly polarized light detection

L Zhang, I Song, J Ahn, M Han, M Linares… - Nature …, 2021 - nature.com
Despite great challenges, the development of new molecular structures with multiple and
even conflicting characteristics are eagerly pursued for exploring advanced applications. To …

Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO-LUMO Separation by the Multiple Resonance Effect.

T Hatakeyama, K Shiren, K Nakajima… - … (Deerfield Beach, Fla …, 2016 - europepmc.org
Ultrapure blue-fluorescent molecules based on thermally activated delayed fluorescence
are developed. Organic light-emitting diode (OLED) devices employing the new emitters …

The added value of small-molecule chirality in technological applications

JR Brandt, F Salerno, MJ Fuchter - Nature Reviews Chemistry, 2017 - nature.com
Chirality is a fundamental symmetry property; chiral objects, such as chiral small molecules,
exist as a pair of non-superimposable mirror images. Although small-molecule chirality is …