Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

A protocol for the oxidation of alcohols to aldehydes and ketones employing an
electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic …

Elusive N-acyl-1, 2, 3-triazoles formed by direct acylation of NH-1, 2, 3-triazoles were
isolated and fully characterized, including X-ray crystallography. A preference for the …

A one-pot procedure for the oxidative amidation of aldehydes via the in situ generation of
reactive nitrile imine (NI) intermediates has been developed. Distinct from our progenitor …

Background: Oxidation is a valuable tool in preparative organic chemistry. Oxoammonium
salts and nitroxides have proven valuable as reagents and catalysts in this endeavor …

Novel acyl pyrazoles and acyl triazoles have been prepared by means of the oxidative
amidation of aldehydes in the presence of the requisite azole. Yields range from modest to …

Amides are adaptable building blocks in synthetic organic chemistry that have a wide range
of medicinal applications. They are also employed as industrial raw materials for the wide …

The [1, 2, 4] triazolo [4, 3-a] pyridine derivative 3-(4-(benzyloxy)-3-methoxyphenyl)-[1, 2, 4]
triazolo [4, 3-a] pyridine was prepared in a 73% isolated yield by means of an oxidative ring …

Amides are universal in nature. Proteins are polymers (polyamides) whose units are
connected by amide (peptide) linkages. Proteins perform innumerable functions in the body …

This work investigates various key oxidation and oxidative functionalization reactions that
occur using a bench-stable nitroxide and its oxoammonium nitrate salt congener. Such …