A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …

Activation and reduction of O2 and H2O2 by synthetic and biosynthetic iron porphyrin
models have proved to be a versatile platform for evaluating second-sphere effects deemed …

Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …

The copper-catalyzed azide–alkyne cycloaddition (CuAAC) is one of the most broadly
applicable and easy-to-handle reactions in the arsenal of organic chemistry. However, the …

In this paper, a new strategy for the construction of multifunctional electrochemical detection
platforms based on the Michael addition/Schiff base reaction of polydopamine modified …

The field of biomimetic chemistry encompasses a wide variety of subfields, including
biomimetic catalysis, bioinspired self-assembly, and biomimetic reactions in total synthesis …

Facile and selective 4e–/4H+ electrochemical reduction of O2 to H2O in aqueous medium
has been a sought-after goal for several decades. Elegant but synthetically demanding …

A mechanistic model is formulated to account for the high reactivity of chelating azides
(organic azides capable of chelation-assisted metal coordination at the alkylated azido …

We report the highly facet‐dependent catalytic activity of Cu2O nanocubes, octahedra, and
rhombic dodecahedra for the multicomponent direct synthesis of 1, 2, 3‐triazoles from the …