Recent advances in transition-metal-catalyzed glycosyl cross-coupling reactions

A Chen, B Yang, Z Zhou, F Zhu - Chem Catalysis, 2022 - cell.com
As one of the effective strategies for carbohydrate synthesis, chemical synthesis can
precisely control the structure of sugar chains, thus establishing the structure-activity …

An Overview on the Chemical N‐Functionalization of Sugars and Formation of N‐Glycosides

R Sangwan, A Khanam… - European Journal of …, 2020 - Wiley Online Library
Its even more than a centennial that the systematic researches of chemical alteration of
sugars have been advancing. Out of all the interest in the field of N‐glycoside has …

Palladium-Catalyzed Regio- and Stereoselective Glycosylation of Azole Heterocycles Enables Access to Diverse Heterocyclic N-Glycosides

Y Xiong, Y Dai - Organic Letters, 2024 - ACS Publications
An efficient and practical glycosylation platform for synthesizing N-glycosides by leveraging
palladium catalysis is disclosed. This approach enables facile access to diverse heterocyclic …

Ru doped hydrotalcite catalyzed borrowing hydrogen-mediated N-alkylation of benzamides, sulfonamides, and dehydrogenative synthesis of quinazolinones

B Sardar, R Jamatia, A Samanta… - The Journal of Organic …, 2022 - ACS Publications
An efficient Ru doped hydrotalcite catalyzed N-alkylation of benzamides and sulfonamides
with alcohols via borrowing hydrogen catalysis is illustrated. Various primary alcohols …

Boron-promoted umpolung reaction of sulfonyl chlorides for the stereospecific synthesis of thioglycosides via reductive deoxygenation coupling reactions

S Li, Y Wang, L Zhong, S Wang, Z Liu, Y Dai… - Organic …, 2022 - ACS Publications
S-Glycosides have broad biological activities and serve as stable mimics of natural O-
glycoside counterparts and thus are of great therapeutic potential. Herein we disclose an …

One‐Pot Stereoselective Synthesis of 2,3,4‐Unprotected β‐N‐Glycopyranosides from Glycals and Amines

J Gao, Y Li, N Wang, Z Li, N Huang… - Advanced Synthesis & …, 2023 - Wiley Online Library
A one‐pot synthesis of 2, 3, 4‐unprotected β‐N‐glycopyranosides from glycals and amines
with exclusive β‐stereoselectivity under room temperature conditions is reported. This …

Facile and stereospecific synthesis of diverse β-N-glycosyl sulfonamide scaffolds via palladium catalysis

L Zhong, Q Wang, Y Wang, Y Cheng, Y Xiong… - Chemical …, 2023 - pubs.rsc.org
Glycosylation is an important strategy to improve the druggability of lead compounds. Here,
we present a palladium-catalysed stereospecific N-glycosylation of sulfonamides. This …

Self-promoted and stereospecific formation of N-glycosides

MM Nielsen, P Mała, EÞ Baldursson… - Chemical Science, 2019 - pubs.rsc.org
A stereoselective and self-promoted glycosylation for the synthesis of various N-glycosides
and glycosyl sulfonamides from trichloroacetimidates is presented. No additional catalysts or …

Convergent palladium-catalyzed stereospecific arginine glycosylation using glycals

J Yang, Y Dai, R Bartlett, Q Zhang - Organic letters, 2021 - ACS Publications
A stereospecific convergent peptide arginine glycosylation method is reported for the first
time. A recently discovered arginine glycosylation invigorated the interests of arginine …

Palladium catalyzed decarboxylative β-C-glycosylation of glycals with oxazol-5-(4 H)-ones as acceptors

WY Ding, HH Liu, JK Cheng, H Yao… - Organic Chemistry …, 2022 - pubs.rsc.org
Despite the increased importance of C-glycosides in biochemistry, the strategy for creating
the C-glycosidic bond stereoselectively has received less attention than that for its O-and N …