Pd‐catalysis has stood as a pivotal force in synthetic transformations for decades,
maintaining its status as a paramount tool in the realm of C− H bond activation. While …

Catalytic systems for direct C− H activation of arenes commonly show preference for
electronically activated and sterically exposed C− H sites. Here we show that a range of …

Bonds between hydrogen and carbon atoms are the most frequent type of bonds in organic
molecules. The ability to replace hydrogen atoms by making other types of bonds to carbon …

The coordination of anionic donors is involved at various stages of catalytic cycles in
transition‐metal catalysis, but control over the spatial positioning of anions around a metal …

Direct transformation of C− H bonds to C− C bonds using transi on metals such as palladium
shows great promise for the synthesis of complex molecules and materials. However, the …