Low tensile strength, poor elastic modulus, and complex concrete cracking work condition
are almost unavoidable due to the intrinsic brittleness. To deal with concrete maintenance …

Six‐coordinated heme groups are involved in a large variety of electron transfer reactions
because of their ability to exist in both the ferrous (Fe2+) and ferric (Fe3+) state without any …

Axial iron ligation and protein encapsulation of the heme cofactor have been investigated as
effectors of the reduction potential (E°') of cytochrome c through direct electrochemistry …

The electrochemical midpoint potentials (E m's) of 13 cytochromes, in globin (c, c 2, c 551, c
553), four-helix bundle (c ', b 562), αβ roll (b5), and β sandwich (f) motifs, with E m's …

The use of Sporosarcina pasteurii to precipitate calcium carbonate in the anoxic subsurface
via ureolysis has been proposed for reducing porosity and sealing fractures in rocks. Here …

The free energy of heme reduction in different proteins is found to vary over more than 18
kcal/mol. It is a challenge to determine how proteins manage to achieve this enormous …

The thermodynamic parameters of protein reduction (Δ H°'rc and ΔS°'rc) were measured for
a number of blue copper proteins including spinach plastocyanin, cucumber plastocyanin …

Cytochromes are a large and well-known group of electron transfer proteins, but only very
few are used in bioelectrochemistry, eg to serve as electron shuttles between biocatalysts …

In Mitchell's chemiosmotic theory, a proton (H+) motive force across the membrane (Δp),
generated by the respiratory chain, drives F1Fo-ATPase for ATP production in various …

Recent evidence has shown that the properties of metal binding sites can be tuned by more
than the ligands in the primary coordination sphere. We investigated the incorporation of …