Metal-metal interactions in correlated single-atom catalysts

J Shan, C Ye, Y Jiang, M Jaroniec, Y Zheng… - Science …, 2022 - science.org
Single-atom catalysts (SACs) include a promising family of electrocatalysts with unique
geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging …

Multi-atom cluster catalysts for efficient electrocatalysis

L Sun, V Reddu, X Wang - Chemical Society Reviews, 2022 - pubs.rsc.org
Multi-atom cluster catalysts have turned out to be novel heterogeneous catalysts with atomic
dispersion for electrochemical energy applications. Beyond a simple combination of single …

Adjacent Fe Site boosts electrocatalytic oxygen evolution at Co site in single-atom-catalyst through a dual-metal-site design

C Chen, M Sun, F Zhang, H Li, M Sun, P Fang… - Energy & …, 2023 - pubs.rsc.org
Co-based single-atom-catalysts have emerged as possible candidates for the oxygen
evolution reaction (OER); however, further improvements in the performance of Co metal …

The significance of properly reporting turnover frequency in electrocatalysis research

S Anantharaj, PE Karthik, S Noda - … Chemie International Edition, 2021 - Wiley Online Library
For decades, turnover frequency (TOF) has served as an accurate descriptor of the intrinsic
activity of a catalyst, including those in electrocatalytic reactions involving both fuel …

Single-atom (iron-based) catalysts: synthesis and applications

B Singh, MB Gawande, AD Kute, RS Varma… - Chemical …, 2021 - ACS Publications
Supported single-metal atom catalysts (SACs) are constituted of isolated active metal
centers, which are heterogenized on inert supports such as graphene, porous carbon, and …

Coexisting single‐atomic Fe and Ni sites on hierarchically ordered porous carbon as a highly efficient ORR electrocatalyst

Z Zhu, H Yin, Y Wang, CH Chuang, L Xing… - Advanced …, 2020 - Wiley Online Library
The development of oxygen reduction reaction (ORR) electrocatalysts based on earth‐
abundant nonprecious materials is critically important for sustainable large‐scale …

Nurturing the marriages of single atoms with atomic clusters and nanoparticles for better heterogeneous electrocatalysis

L Zhang, J Zhu, X Li, S Mu, F Verpoort… - Interdisciplinary …, 2022 - Wiley Online Library
Single‐atom catalysts, featuring some of the most unique activities, selectivity, and high
metal utilization, have been extensively studied over the past decade. Given their high …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Tackling the activity and selectivity challenges of electrocatalysts toward the nitrogen reduction reaction via atomically dispersed biatom catalysts

X Guo, J Gu, S Lin, S Zhang, Z Chen… - Journal of the American …, 2020 - ACS Publications
Developing efficient catalysts for nitrogen fixation is becoming increasingly important but is
still challenging due to the lack of robust design criteria for tackling the activity and selectivity …

Tailoring of active sites from single to dual atom sites for highly efficient electrocatalysis

H Zhang, X Jin, JM Lee, X Wang - ACS nano, 2022 - ACS Publications
Single atom catalysts (SACs) have been attracting extensive attention in electrocatalysis
because of their unusual structure and extreme atom utilization, but the low metal loading …