Emerging catalytic processes for the production of adipic acid

S Van de Vyver, Y Román-Leshkov - Catalysis Science & Technology, 2013 - pubs.rsc.org
Research efforts to find more sustainable pathways for the synthesis of adipic acid have led
to the introduction of new catalytic processes for producing this commodity chemical from …

[HTML][HTML] Advances in the synthesis of acyclic peroxides

H Gandhi, K O'Reilly, MK Gupta, C Horgan… - RSC …, 2017 - pubs.rsc.org
Peroxide-containing compounds are an attractive synthetic target, given their widespread
abundance in nature, with many displaying potent antimalarial and antimicrobial properties …

Stereoelectronic effects in the formation of 5-and 6-membered rings: the role of Baldwin's rules

CD Johnson - Accounts of chemical research, 1993 - ACS Publications
The demonstration by Dunitz and hisco-workers1 of favored trajectories for the approach of
one reactant molecule toward another led to the formulation of rules governing the ease of …

Triflic Acid‐Functionalized Silica‐Coated Magnetic Nanoparticles as a Magnetically Separable Catalyst for Synthesis of gem‐Dihydroperoxides

YH Liu, J Deng, JW Gao… - Advanced Synthesis & …, 2012 - Wiley Online Library
Triflic acid‐functionalized silica‐coated magnetic nanoparticles [γ‐Fe2O3@ SiO2‐TfOH]
were readily prepared and identified as an effictive catalyst for the transformation of …

Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect

E Juaristi, G dos Passos Gomes… - Journal of the …, 2017 - ACS Publications
The first systematic study of the intramolecular α-effect, both in the stable ground-state
structures and in the high-energy intermediates, was accomplished using the anomeric …

Synthetic Peroxides Promote Apoptosis of Cancer Cells by Inhibiting P‐Glycoprotein ABCB5

IA Yaremenko, P Coghi, P Prommana, C Qiu… - …, 2020 - Wiley Online Library
This article discloses a new horizon for the application of peroxides in medical chemistry.
Stable cyclic peroxides are demonstrated to have cytotoxic activity against cancer cells; in …

Catalyst development for the synthesis of ozonides and tetraoxanes under heterogeneous conditions: Disclosure of an unprecedented class of fungicides for …

IA Yaremenko, PS Radulov… - … A European Journal, 2020 - Wiley Online Library
Abstract The catalyst H3+ xPMo12− x+ 6Mox+ 5O40 supported on SiO2 was developed for
peroxidation of 1, 3‐and 1, 5‐diketones with hydrogen peroxide with the formation of …

Cyclic peroxides as promising anticancer agents: In vitro cytotoxicity study of synthetic ozonides and tetraoxanes on human prostate cancer cell lines

IA Yaremenko, MA Syroeshkin, DO Levitsky… - Medicinal Chemistry …, 2017 - Springer
Synthetic ozonides and tetraoxanes were shown to have high cytotoxicity in vitro when
tested on androgen-independent prostate cancer cell lines DU145 and PC3, which is in …

Stereoelectronic control in the ozone‐free synthesis of ozonides

G dos Passos Gomes, IA Yaremenko… - Angewandte …, 2017 - Wiley Online Library
The value of stereoelectronic guidelines is illustrated by the discovery of a convenient,
ozone‐free synthesis of bridged secondary ozonides from 1, 5‐dicarbonyl compounds and …

Mild and efficient Re (VII)-catalyzed synthesis of 1, 1-dihydroperoxides

P Ghorai, PH Dussault - Organic Letters, 2008 - ACS Publications
Re2O7 in CH3CN is a remarkably efficient and mild catalyst for the peroxyacetalization of
ketones, aldehydes, or acetals by H2O2 to generate 1, 1-dihydroperoxides. Me3SiOReO3 …