Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Oxycarbenes have emerged as useful intermediates in synthetic chemistry. Compared to the
widely studied oxycarbene metal complexes bearing Group 6 metals, the synthetic and …

Although the synthesis of common cyclopropenes has been well studied, the access to
cyclopropenols is rather limited. Herein, we report the first synthesis of α‐trifluoromethylated …

Visible light induced singlet nucleophilic carbenes undergo rapid [2+ 1]-cycloaddition with
tethered olefins to afford unique bicyclo [3.1. 0] hexane and bicyclo [4.1. 0] heptane …

Acylsilanes have been utilized in various transformations for the synthesis of functionalized
organosilicon derivatives due to their importance in medicinal and materials science. This …

Investigations into C− H amidation reactions catalysed by cationic half‐sandwich d6 metal
complexes revealed that the indenyl‐derived catalyst [Ind* RhCl2] 2 significantly accelerated …

A novel methodology for in situ generation of Fischer-type metal–carbene complexes was
developed. Photoirradiation to a mixture of an acylsilane and a cationic copper complex …

In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

Herein, we report a divergent synthesis of fluoroalkyl ketones through visible-light-induced
reactions between readily available organoboronic esters and fluoroalkyl acylsilanes …

Herein we report the first [4+ 1] cyclization-aromatization reaction of acylsilanes and α, β-
unsaturated ketones. The unprecedented visible-light-induced reaction proceeded through …