[HTML][HTML] Recent advances in the synthesis of selenophenes and their derivatives

PS Hellwig, TJ Peglow, F Penteado, L Bagnoli, G Perin… - Molecules, 2020 - mdpi.com
The selenophene derivatives are an important class of selenium-based heterocyclics. These
compounds play an important role in prospecting new drugs, as well as in the development …

Biologically active selenophenes and benzo [b] selenophenes

AB Abdelwahab Mahmoud, G Kirsch… - Current Organic …, 2017 - ingentaconnect.com
Background: During the last decade, numerous research has indicated a promising
perspective for selenophene and benzo [b] selenophene (BBS) as a promising scaffold for …

Rongalite in PEG-400 as a general and reusable system for the synthesis of 2, 5-disubstituted chalcogenophenes

DB Paixão, EGO Soares, HD Salles… - Organic Chemistry …, 2022 - pubs.rsc.org
In this work, we report the use of rongalite in PEG-400 as a general, reusable, efficient,
inexpensive and environmentally benign reductive system for elemental chalcogens and its …

Iron‐Promoted Tandem Cyclization of 1,3‐Diynyl Chalcogen Derivatives with Diorganyl Dichalcogenides for the Synthesis of Benzo[b]furan‐Fused Selenophenes

JSS Neto, BA Iglesias, DF Back… - Advanced Synthesis & …, 2016 - Wiley Online Library
A double intramolecular 5‐endo‐dig cyclization of butyl [2‐(phenylbuta‐1, 3‐diynyl) phenyl]
chalcogens has been employed in a selective preparation of benzo [b] chalcogenopheno [2 …

Synthesis of 5H‐Selenopheno[3,2‐c]isochromen‐5‐ones Promoted by Dialkyl Diselenides and Oxone®

HA Goulart, JSS Neto, AM Barcellos… - Advanced Synthesis …, 2019 - Wiley Online Library
We describe here for the first time the synthesis of isochromenones fused to selenophenes.
5H‐Selenopheno [3, 2‐c] isochromen‐5‐ones were obtained through a double …

Electrophilic cyclization involving carbon–selenium/carbon–halide bond formation: Synthesis of 3-substituted selenophenes

KK Casola, MR Gomes, DF Back… - The Journal of Organic …, 2018 - ACS Publications
The butylselanyl propargyl alcohols reacted with iodine to afford 3-iodoselenophenes. The
change of nucleophile position from propargyl to homopropargyl was crucial for the …

[HTML][HTML] 2, 2′-Dithienyl diselenide pro-oxidant activity accounts for antibacterial and antifungal activities

AP Pesarico, G Sartori, CFA dos Santos, JSS Neto… - Microbiological …, 2013 - Elsevier
The aim of this study was to explore if 2, 2′-dithienyl diselenide (DTDS) pro-oxidant activity
is related to its antibacterial and antifungal actions. The antimicrobial activity of DTDS …

Synthesis of Chalcogenophenes via Cyclization of 1,3‐Diynes Promoted by Iron(III) Chloride and Dialkyl Dichalcogenides

FN Bilheri, AL Stein, G Zeni - Advanced Synthesis & Catalysis, 2015 - Wiley Online Library
In this paper, we report the iron (III) chloride and dibutyl diselenide‐mediated cyclization of
1, 3‐diynes which leads to 3, 4‐bis (butylselanyl) selenophenes. The optimization studies …

Synthesis of benzo [b] chalcogenophenes fused to selenophenes via intramolecular electrophilic cyclization of 1, 3-diynes

PS Hellwig, JS Guedes, AM Barcellos… - Organic & …, 2021 - pubs.rsc.org
We describe herein an alternative and transition-metal-free procedure for the access of
benzo [b] chalcogenophenes fused to selenophenes via intramolecular cyclization of 1, 3 …

Iron‐Mediated Cyclization of 1, 3‐Diynyl Propargyl Aryl Ethers with Dibutyl Diselenide: Synthesis of Selenophene‐Fused Chromenes

G Lutz, DF Back, G Zeni - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
The synthesis of selenophene‐fused chromene derivatives starting from 1, 3‐diynyl
propargyl aryl ethers is reported herein. The method is based on carbon‐carbon, carbon …