Metal-catalyzed intermolecular hydrofunctionalization of allenes: easy access to allylic structures via the selective formation of C–N, C–C, and C–O bonds

R Blieck, M Taillefer, F Monnier - Chemical Reviews, 2020 - ACS Publications
Following a strong regain of interest over the past 20 years in the chemistry of allenes, this
“forgotten” family of unsaturated molecules is undergoing a renaissance. In this context, the …

Mass spectrometry using electrospray ionization

GRD Prabhu, ER Williams, M Wilm… - Nature Reviews Methods …, 2023 - nature.com
Applying a high voltage to a liquid passing through a capillary disintegrates the liquid
meniscus to generate a fine spray of charged droplets. As the droplets evaporate, polar …

Allenes in catalytic asymmetric synthesis and natural product syntheses

S Yu, S Ma - Angewandte Chemie International Edition, 2012 - Wiley Online Library
Allenes are the simplest class of cumulenes, with two contiguous C C bonds, and show
unique physical and chemical properties. These features make allenes particularly attractive …

Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C− X coupling reactions …

DV Partyka - Chemical Reviews, 2011 - ACS Publications
Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Allenes and computational chemistry: from bonding situations to reaction mechanisms

E Soriano, I Fernández - Chemical Society Reviews, 2014 - pubs.rsc.org
The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …

Facile regio-and stereoselective hydrometalation of alkynes with a combination of carboxylic acids and group 10 transition metal complexes: selective hydrogenation …

R Shen, T Chen, Y Zhao, R Qiu, Y Zhou… - Journal of the …, 2011 - ACS Publications
A facile, highly stereo-and regioselective hydrometalation of alkynes generating
alkenylmetal complex is disclosed for the first time from a reaction of alkyne, carboxylic acid …

[PDF][PDF] Chemoselective Transfer Hydrogenation to Nitroarenes Mediated by Cubane‐Type Mo3S4 Cluster Catalysts

I Sorribes, G Wienhöfer, C Vicent, K Junge… - Angewandte Chemie …, 2012 - academia.edu
Functionalized anilines are valuable intermediates for the manufacture of dyes, pigments,
agrochemicals, and pharmaceuticals.[1] Furthermore, they represent key precursors for the …

Allene in katalytischer asymmetrischer Synthese und Naturstoffsynthese

S Yu, S Ma - Angewandte Chemie, 2012 - Wiley Online Library
Allene–Verbindungen mit zwei benachbarten C C‐Bindungen–bilden die einfachste
Klasse unter den Cumulenen. Sie verfügen über außergewöhnliche physikalische und …

Chemical reaction monitoring by ambient mass spectrometry

J Sun, Y Yin, W Li, O Jin, N Na - Mass Spectrometry Reviews, 2022 - Wiley Online Library
Chemical reactions conducted in different media (liquid phase, gas phase, or surface) drive
developments of versatile techniques for the detection of intermediates and prediction of …

Three Carbons for Complexity! Recent Developments of Palladium‐Catalyzed Reactions of Allenes

T Lechel, F Pfrengle, HU Reissig, R Zimmer - ChemCatChem, 2013 - Wiley Online Library
The three carbon atoms of allene moieties allow unique transformations and rapid
generation of complexity. Not surprisingly, allenes became extremely versatile building …