Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction

Z Zeb, Y Huang, L Chen, W Zhou, M Liao… - Coordination Chemistry …, 2023 - Elsevier
Electrocatalytic water splitting via hydrogen evolution reaction (HER) from renewable energy
sources is an attractive alternative to produce hydrogen, but it still encounters the limitations …

Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

JM Cameron, G Guillemot, T Galambos… - Chemical Society …, 2022 - pubs.rsc.org
This review provides a comprehensive overview of recent advances in the supramolecular
organisation and hierarchical self-assembly of organo-functionalised hybrid …

Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures

F Ai, Z Wang, NC Lai, Q Zou, Z Liang, YC Lu - Nature Energy, 2022 - nature.com
Operating aqueous redox flow batteries (ARFBs) at low temperatures is prohibited by limited
solubility of redox-active materials, freezing electrolytes and sluggish reaction kinetics. Here …

Polyoxometalates in solution: speciation under spotlight

NI Gumerova, A Rompel - Chemical Society Reviews, 2020 - pubs.rsc.org
Polyoxometalates (POMs) are a large group of anionic polynuclear metal–oxo clusters with
discrete and chemically modifiable structures. In most aqueous POM solutions, numerous …

Recent advances in the development of electronically and ionically conductive metal-organic frameworks

G Zhang, L Jin, R Zhang, Y Bai, R Zhu… - Coordination Chemistry …, 2021 - Elsevier
As porous materials, metal–organic frameworks (MOFs) have drawn increased attention and
are widely applied in various fields such as catalysis, gas/energy storage, chemical sensing …

Recent advances in confining polyoxometalates and the applications

L Guo, L He, Q Zhuang, B Li, C Wang, Y Lv, J Chu… - Small, 2023 - Wiley Online Library
Polyoxometalates (POMs) are widely used in catalysis, energy storage, biomedicine, and
other research fields due to their unique acidity, photothermal, and redox features. However …

Heterogeneous catalysis by polyoxometalates in metal–organic frameworks

M Samaniyan, M Mirzaei, R Khajavian… - ACS …, 2019 - ACS Publications
The embedding of molecular metal oxides, or polyoxometalates (POMs), in metal–organic
frameworks (MOFs) opens new research avenues in catalysis and beyond. This review …

Speciation atlas of polyoxometalates in aqueous solutions

NI Gumerova, A Rompel - Science Advances, 2023 - science.org
Speciation is the key parameter in solution chemistry that describes the composition,
concentration, and oxidation state of each chemical form of an element present in a sample …

Polyoxometalate‐soft matter composite materials: design strategies, applications, and future directions

JH Kruse, M Langer, I Romanenko… - Advanced functional …, 2022 - Wiley Online Library
Molecular metal oxides or polyoxometalates (POMs) offer unrivaled properties in areas
ranging from catalysis and energy conversion through to molecular electronics, biomimetics …

Core‐Shell‐Type All‐Inorganic Heterometallic Nanoclusters: Record High‐Nuclearity Cobalt Polyoxoniobates for Visible‐Light‐Driven Photocatalytic CO2 Reduction

ZW Guo, LH Lin, JP Ye, Y Chen, XX Li, S Lin… - Angewandte …, 2023 - Wiley Online Library
Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …