Pyrolysis study of dimethyl carbonate, diethyl carbonate, and ethyl methyl carbonate using shock-tube spectroscopic CO measurements and chemical kinetics …

CM Grégoire, SP Cooper, M Khan-Ghauri… - Combustion and …, 2023 - Elsevier
The pyrolysis of three linear carbonates-dimethyl carbonate (DMC), diethyl carbonate
(DEC), and ethyl methyl carbonate (EMC)-was investigated behind reflected shock waves …

Experimental investigation of the combustion properties of an average thermal runaway gas mixture from li-ion batteries

O Mathieu, CM Grégoire, MA Turner, DJ Mohr… - Energy & …, 2022 - ACS Publications
To assess the fire hazard associated with venting gases coming from a lithium-ion battery
during a thermal runaway, a mixture representative of such venting gas was determined by …

Comparison of methane combustion mechanisms using shock tube and rapid compression machine ignition delay time measurements

P Zhang, IG Zsély, V Samu, T Nagy, T Turányi - Energy & Fuels, 2021 - ACS Publications
Methane is the major component of natural gas, which is one of the most widely used fuels.
A large number of shock tube (ST) and rapid compression machine (RCM) ignition delay …

A wide range experimental study and further development of a kinetic model describing propane oxidation

L Zhu, S Panigrahy, SN Elliott, SJ Klippenstein… - Combustion and …, 2023 - Elsevier
This work presents an experimental and kinetic modeling study of propane oxidation.
Ignition delay times of propane were measured in a high-pressure shock tube and in rapid …

Shock-tube CO measurements during the pyrolysis of ethylene carbonate

CM Grégoire, EL Petersen, O Mathieu - Combustion and Flame, 2023 - Elsevier
Ethylene carbonate (EC) is a key component of the flammable electrolyte in lithium-ion
batteries. In this study, the pyrolysis of ethylene carbonate was investigated by measuring …

Laminar flame speed and shock-tube multi-species laser absorption measurements of Dimethyl Carbonate oxidation and pyrolysis near 1 atm

T Atherley, S De Persis, N Chaumeix… - Proceedings of the …, 2021 - Elsevier
Dimethyl Carbonate (DMC) is a carbonate ester that can be produced in an environment-
friendly way from methanol and CO 2. DMC is one of the main components of the flammable …

Speciation measurements in shock tubes for validation of complex chemical kinetics mechanisms: Application to 2-Methyl-2-Butene oxidation

SA Alturaifi, CR Mulvihill, O Mathieu, EL Petersen - Combustion and Flame, 2021 - Elsevier
Shock-tube species time histories can be used to generate multiple validation targets to
develop and validate detailed chemical kinetics mechanisms. In this study, new shock-tube …

Experimental and modeling study of the combustion of ethyl methyl carbonate, a battery electrolyte

CM Grégoire, YM Almarzooq, EL Petersen… - Combustion and …, 2024 - Elsevier
Ethyl methyl carbonate (EMC) is one of the main constituents of the electrolyte in lithium-ion
batteries (LIBs). To understand better fire events involving LIBs and try to prevent them, the …

Multi-isotopologue laser absorption spectroscopy of carbon monoxide for high-temperature chemical kinetic studies of fuel mixtures

DI Pineda, FA Bendana, KK Schwarm… - Combustion and …, 2019 - Elsevier
A laser absorption diagnostic technique, probing the mid-infrared vibrational bands of 12 C
16 O and 13 C 16 O near 4.9 µm, was developed for sensitive multi-isotopologue …

Chemical kinetics investigation of toluene combustion in a shock tube using spectroscopic CO and H2O laser absorption

CM Grégoire, SP Cooper, EL Petersen - Fuel, 2023 - Elsevier
Toluene oxidation was investigated behind reflected shock waves using spectroscopic laser
diagnostics to simultaneously measure carbon monoxide (CO) and water (H 2 O) time …