Divergent strategy in natural product total synthesis

L Li, Z Chen, X Zhang, Y Jia - Chemical reviews, 2018 - ACS Publications
The divergent total syntheses of complex natural products from a common intermediate have
attracted enormous attention in the chemical community in the past few years because it can …

Dearomative logic in natural product total synthesis

CJ Huck, YD Boyko, D Sarlah - Natural product reports, 2022 - pubs.rsc.org
Covering: 2011 to 2022 The natural world is a prolific source of some of the most interesting,
rare, and complex molecules known, harnessing sophisticated biosynthetic machinery …

The value of universally available raw NMR data for transparency, reproducibility, and integrity in natural product research

JB McAlpine, SN Chen, A Kutateladze… - Natural product …, 2019 - pubs.rsc.org
Covering: up to 2018 With contributions from the global natural product (NP) research
community, and continuing the Raw Data Initiative, this review collects a comprehensive …

Total synthesis of longeracinphyllin A

J Li, W Zhang, F Zhang, Y Chen… - Journal of the American …, 2017 - ACS Publications
The first and asymmetric total synthesis of longeracinphyllin A, a hexacyclic Daphniphyllum
alkaloid, has been accomplished. A tetracyclic intermediate was prepared through silver …

Asymmetric Total Synthesis of (−)-Arborisidine and (−)-19-epi-Arborisidine Enabled by a Catalytic Enantioselective Pictet–Spengler Reaction

R Andres, Q Wang, J Zhu - Journal of the American Chemical …, 2020 - ACS Publications
A five-step total synthesis of arborisidine, a caged pentacyclic monoterpene indole alkaloid,
has been accomplished in both racemic and enantioselective manners. The synthesis …

Total synthesis of hybridaphniphylline B

W Zhang, M Ding, J Li, Z Guo, M Lu… - Journal of the …, 2018 - ACS Publications
Hybridaphniphylline B (1) is a Daphniphyllum alkaloid possessing 11 rings and 19
stereocenters. Here we report the first total synthesis of 1 featuring a late-stage …

Total synthesis of Aplysiasecosterol A

Z Lu, X Zhang, Z Guo, Y Chen, T Mu… - Journal of the American …, 2018 - ACS Publications
Aplysiasecosterol A (1) is a structurally unusual 9, 11-secosteroid isolated from the sea hare
Aplysia kurodai. We have accomplished the first and asymmetric total synthesis of 1 in a …

Asymmetric Total Synthesis of (+)-Alstonlarsine A

JJ Yao, R Ding, X Chen, H Zhai - Journal of the American …, 2022 - ACS Publications
The first asymmetric total synthesis of (+)-alstonlarsine A has been realized. The prominent
features of the current synthesis include the following:(i) a Pd/self-adaptable ligand complex …

[HTML][HTML] Recent advances in the total synthesis of monoterpenoid indole alkaloids enabled by asymmetric catalysis

XY Liu, Y Qin - Green Synthesis and Catalysis, 2022 - Elsevier
Asymmetric catalysis has continued to enable the preparation of optically active natural
products over the past decade. This minireview summarizes progress in the catalytic …

Total syntheses of aflavazole and 14-hydroxyaflavinine

H Li, Q Chen, Z Lu, A Li - Journal of the American Chemical …, 2016 - ACS Publications
The first total syntheses of aflavazole (6) and 14-hydroxyaflavinine (8), two sterically
congested indole diterpenoids, were accomplished. AlI3-promoted alkyne Prins cyclization …