Manipulating nonadiabatic conical intersection dynamics by optical cavities

B Gu, S Mukamel - Chemical science, 2020 - pubs.rsc.org
Optical cavities hold great promise to manipulate and control the photochemistry of
molecules. We demonstrate how molecular photochemical processes can be manipulated …

Polariton ring currents and circular dichroism of Mg-porphyrin in a chiral cavity

S Sun, B Gu, S Mukamel - Chemical Science, 2022 - pubs.rsc.org
By placing Mg-porphyrin molecules in a chiral optical cavity, time reversal symmetry is
broken, and polariton ring currents can be generated with linearly polarized light, resulting in …

Theory for nonlinear spectroscopy of vibrational polaritons

R F. Ribeiro, AD Dunkelberger, B Xiang… - The journal of …, 2018 - ACS Publications
Molecular polaritons have gained considerable attention due to their potential to control
nanoscale molecular processes by harnessing electromagnetic coherence. Although recent …

Organic photodiodes with an extended responsivity using ultrastrong light–matter coupling

E Eizner, J Brodeur, F Barachati, A Sridharan… - ACS …, 2018 - ACS Publications
In organic photodiodes (OPDs), light is absorbed by excitons that dissociate to generate
photocurrent. Here, we demonstrate a novel type of OPD in which light is absorbed by …

Angle-independent polariton emission lifetime shown by perylene hybridized to the vacuum field inside a Fabry–Pérot cavity

J Mony, M Hertzog, K Kushwaha… - The Journal of Physical …, 2018 - ACS Publications
The formation of hybrid light–matter states in optical structures, manifested as a Rabi
splitting of the eigenenergies of a coupled system, is one of the key effects in quantum …