Chemistry is the science of bond making and bond breaking. A thorough knowledge of these
processes in the course of the chemical reaction lies at the heart of any reaction mechanism …

The chemistry of superacids has developed in the last two decades into a field of growing
interest and importance. Now available in a new expanded second edition, this definitive …

Directing groups that can act as internal oxidants have recently been shown to be beneficial
in metal-catalyzed heterocycle syntheses that undergo C− H functionalization. Pursuant to …

An efficient Rh (III)-catalyzed oxidative olefination by directed C− H bond activation of N-
methoxybenzamides is reported. In this mild, practical, selective, and high-yielding process …

This review aims to be a comprehensive, authoritative, critical, and accessible review of
general interest to the chemistry community; because the electrophilicity index is a very …

Chemistry is the science of bond making and bond breaking. A thorough knowledge of these
processes in the course of the chemical reaction lies at the heart of any reaction mechanism …

Reported is an achiral CpxRhIII/chiral carboxylic acid catalyzed asymmetric C− H alkylation
of diarylmethanamines with a diazomalonate, followed by cyclization and decarboxylation to …

The chemistry of cinnamic acids and related compounds has been studied. In superacid-
catalyzed reactions with arenes, two competing reaction mechanisms are proposed. Both …

The reaction of benzamides with alkynes assisted by an 8-aminoquinoline ligand in the
presence of Co (OAc) 2· 4H2O and pivalic acid under an air atmosphere provided …

Cyclometalation of 3-(2-naphthyl)-d-alanine methyl ester is achieved by reacting the
corresponding hydrochloride salt and Pd (OAc) 2 in a 1: 1 molar ratio (acetonitrile, room …