Enzymatic polymerization

S Kobayashi, H Uyama, S Kimura - Chemical reviews, 2001 - ACS Publications
There has been an exponential increase in interest in the area of in vitro enzyme-catalyzed
organic reactions, since many families of enzymes can be utilized for transformation of not …

A retrosynthesis approach for biocatalysis in organic synthesis

ROMA de Souza, LSM Miranda… - … –A European Journal, 2017 - Wiley Online Library
For the planning of an organic synthesis route, the disconnection approach guided by
retrosynthetic analysis of possible intermediates and the chemical reactions involved, back …

C− C bond-forming lyases in organic synthesis

M Brovetto, D Gamenara, P Saenz Mendez… - Chemical …, 2011 - ACS Publications
Lyases are enzymes that catalyze the bond construction and breaking by means other than
hydrolysis or redox reactions. Such enzymes are particular in the sense that they only …

Synthesis and applications of non-racemic cyanohydrins

M North - Tetrahedron: Asymmetry, 2003 - Elsevier
Methods for the catalytic asymmetric synthesis of cyanohydrins derived from both aldehydes
and ketones are reviewed. Successful catalysts based on enzymes, peptides and …

Systematic design and in vitro validation of novel one-carbon assimilation pathways

X Yang, Q Yuan, H Luo, F Li, Y Mao, X Zhao, J Du… - Metabolic …, 2019 - Elsevier
The utilization of one-carbon (C 1) assimilation pathways to produce chemicals and fuels
from low-cost C 1 compounds could greatly reduce the substrate-related production costs …

Density functional study of the proline-catalyzed direct aldol reaction

KN Rankin, JW Gauld, RJ Boyd - The Journal of Physical …, 2002 - ACS Publications
The proline-catalyzed direct aldol reaction between acetone and acetaldehyde has been
investigated using density functional theory. Proline catalyzes the reaction according to the …

Enantioselective C–C bond synthesis catalysed by enzymes

J Sukumaran, U Hanefeld - Chemical Society Reviews, 2005 - pubs.rsc.org
The enantioselective synthesis of C–C bonds is often the pivotal step of a synthesis. Nature
has made a variety of versatile enzymes available that catalyse this type of reaction very …

[PDF][PDF] Biocatalytic Friedel–Crafts Alkylation Using Non‐natural Cofactors

H Stecher, M Tengg, BJ Ueberbacher… - Angewandte …, 2009 - graz.elsevierpure.com
The formation of CÀC bonds is a central aspect of synthetic organic chemistry. However, in
biocatalysis only few enzymes capable to perform this reaction are known, among which …

Metal catalyzed asymmetric cyanation reactions

HK Noor-ul, RI Kureshy, SHR Abdi, S Agrawal… - Coordination Chemistry …, 2008 - Elsevier
Chiral cyanohydrins are versatile building blocks for pharmaceuticals, agrochemicals and
specialty materials. A number of efficient and successful synthetic methods have been …

Recent advances regarding the physiological functions and biosynthesis of D-allulose

Z Chen, XD Gao, Z Li - Frontiers in Microbiology, 2022 - frontiersin.org
D-Allulose, a generally regarded as safe (GRAS) sugar, is rare in nature. It is among the
most promising sweeteners for future use due to its low caloric content, sucrose-like taste …