[HTML][HTML] Physical aging in molecular glasses beyond the α relaxation

V Di Lisio, VM Stavropoulou… - The Journal of Chemical …, 2023 - pubs.aip.org
The description of kinetics of physical aging, namely the slow evolution of a glass
thermodynamic state toward equilibrium, generally relies on the exclusive role of the main α …

Degradation of polyethylene terephthalate microplastics by mineral acids: experimental, molecular modelling and optimization studies

T Chowdhury, Q Wang, CE Enyoh - Journal of Polymers and the …, 2022 - Springer
Mineral acids in the atmosphere breakdown on the action of oxygen and release acid gases
into atmosphere causing acid rain, which can chemically weather materials. We …

Polymers of Intrinsic Microporosity─ Molecular Mobility and Physical Aging Revisited by Dielectric Spectroscopy and X-ray Scattering

F Emamverdi, H Yin, GJ Smales, WJ Harrison… - …, 2022 - ACS Publications
Polymers of intrinsic microporosity (PIMs) are promising candidates for the active layer in
gas separation membranes due to their high permeability and reasonable permselectivity …

Network dynamics: a computational framework for the simulation of the glassy state

GG Vogiatzis, LCA van Breemen, M Hütter… - … Systems Design & …, 2023 - pubs.rsc.org
An out-of-equilibrium simulation method for tracking the time evolution of glassy systems (or
any other systems that can be described by hopping dynamics over a network of discrete …

Physical aging of PC: PS blends: Dynamic mechanical analysis and nuclear magnetic resonance studies

I Charif, N Doulache, A Gourari… - Polymer Engineering …, 2022 - Wiley Online Library
The effect of physical aging of the partially miscible blend of polycarbonate: polystyrene (PC:
PS) at temperatures near the glass transition temperature (T g) of the PS was studied as a …

Relationship between recovered enthalpy and the shape‐memory effect in shape memory polymers

M Siwakoti, RW Mailen - Journal of Applied Polymer Science, 2023 - Wiley Online Library
Shape memory polymers (SMPs) maintain a temporary shape after pre‐straining, wherein
the polymer chains are constrained in a non‐equilibrium thermodynamic state. Physical …

Response of elementary structural transitions in glassy atactic polystyrene to temperature and deformation

GG Vogiatzis, LCA van Breemen… - The Journal of Physical …, 2022 - ACS Publications
The effects of temperature, pressure, and imposed strain on the structural transition
pathways of glassy atactic polystyrene (aPS) are studied for a wide range of conditions. By …

Structural transitions in glassy atactic polystyrene using transition-state theory

GG Vogiatzis, LCA van Breemen… - The Journal of Physical …, 2021 - ACS Publications
Transition pathways on the energy landscape of atactic polystyrene (aPS) glassy specimens
are probed below its glass-transition temperature. Each of these transitions is considered an …

Vitrification and physical aging in polymer glasses by broadband dielectric spectroscopy

D Cangialosi - Broadband Dielectric Spectroscopy: A Modern …, 2021 - ACS Publications
Physical aging is an ubiquitous phenomenon in glasses. It takes place on liquids previously
cooled down below their melting temperature and subsequently further cooled below their …

Investigation of electrical ageing effects on the structural and electrical properties of polystyrene by charging and discharging current method

A Hedir, F Slimani, M Moudoud, O Lamrous… - Physica …, 2024 - iopscience.iop.org
This study focuses on isothermal charging and discharging currents in polystyrene (PS). It is
a well known fact that the discharging current is almost the mirror symmetry of the charging …