Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

A historical perspective on porphyrin-based metal–organic frameworks and their applications

X Zhang, MC Wasson, M Shayan… - Coordination chemistry …, 2021 - Elsevier
Porphyrins are important molecules widely found in nature in the form of enzyme active sites
and visible light absorption units. Recent interest in using these functional molecules as …

Stable metal–organic frameworks: design, synthesis, and applications

S Yuan, L Feng, K Wang, J Pang, M Bosch… - Advanced …, 2018 - Wiley Online Library
Metal–organic frameworks (MOFs) are an emerging class of porous materials with potential
applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous …

Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents

NS Bobbitt, ML Mendonca, AJ Howarth… - Chemical Society …, 2017 - pubs.rsc.org
Owing to the vast diversity of linkers, nodes, and topologies, metal–organic frameworks can
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …

Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis

GC Shearer, S Chavan, S Bordiga, S Svelle… - Chemistry of …, 2016 - ACS Publications
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …

[HTML][HTML] Data-informed discovery of hydrolytic nanozymes

S Li, Z Zhou, Z Tie, B Wang, M Ye, L Du, R Cui… - Nature …, 2022 - nature.com
Nanozyme is a collection of nanomaterials with enzyme-like activity but higher
environmental tolerance and long-term stability than their natural counterparts. Improving …

Zirconium-based metal–organic frameworks for the catalytic hydrolysis of organophosphorus nerve agents

KO Kirlikovali, Z Chen, T Islamoglu… - … applied materials & …, 2020 - ACS Publications
Organophoshorus nerve agents are among the most toxic chemicals known to humans, and
because of their unfortunate recent use despite international bans, there is an urgent need …

Stable metal–organic frameworks with group 4 metals: current status and trends

S Yuan, JS Qin, CT Lollar, HC Zhou - ACS central science, 2018 - ACS Publications
Group 4 metal-based metal–organic frameworks (MIV-MOFs), including Ti-, Zr-, and Hf-
based MOFs, are one of the most attractive classes of MOF materials owing to their superior …

Catalytic zirconium/hafnium-based metal–organic frameworks

M Rimoldi, AJ Howarth, MR DeStefano, L Lin… - Acs …, 2017 - ACS Publications
Metal–organic frameworks (MOFs) are highly versatile materials that find applications in
several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and …