Recent advances in the synthesis of insect pheromones: An overview from 2013 to 2022

JPA Souza, PT Bandeira, J Bergmann… - Natural Product …, 2023 - pubs.rsc.org
Covering: 2013 to June 2022 Pheromones are usually produced by insects in sub-
microgram amounts, which prevents the elucidation of their structures by nuclear magnetic …

Stereodivergent routes in organic synthesis: marine natural products, lactones, other natural products, heterocycles and unnatural compounds

C Nájera, F Foubelo, JM Sansano… - Organic & Biomolecular …, 2020 - pubs.rsc.org
Enantio-and diastereodivergent routes to marine-origin natural products with different sizes
of cyclic ethers and lactones have been used in order to assign stereochemical features …

Enantioselective halolactonization reactions using binol-derived bifunctional catalysts: Methodology, diversification, and applications

DW Klosowski, JC Hethcox, DH Paull… - The Journal of …, 2018 - ACS Publications
A general protocol is described for inducing enantioselective halolactonizations of
unsaturated carboxylic acids using novel bifunctional organic catalysts derived from a chiral …

Synthesis of (+)-Disparlure via Enantioselective Iodolactonization

DW Klosowski, SF Martin - Organic letters, 2018 - ACS Publications
The BINOL-amidine organic catalyst 1 was previously shown to promote highly efficient
enantioselective halolactonization reactions of olefinic acids. As part of these studies, it was …

Three decades of disparlure and analogue synthesis

RA Fernandes, N Chandra, AJ Gangani - New Journal of Chemistry, 2020 - pubs.rsc.org
In this review, we have described various syntheses of disparlure (a sex pheromone emitted
by female gypsy moth) and its stereoisomers and analogues over the last three decades …

Synthesis of Isotopically Labelled Disparlure Enantiomers and Application to the Study of Enantiomer Discrimination in Gypsy Moth Pheromone‐Binding Proteins

GR Pinnelli, M Terrado, NK Hillier… - European Journal of …, 2019 - Wiley Online Library
To study the binding mechanism of disparlure (7, 8)‐epoxy‐2‐methyloctadecane
enantiomers with pheromone‐binding proteins (PBPs) of the gypsy moth, oxygen‐17 or 18 …

Organocatalyzed epoxidation in the total synthesis of (−)-trans-,(+)-trans-and (+)-cis-disparlures

A Sharma, SK Pandey - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
A simple, flexible and efficient organocatalyzed synthetic approach for the synthesis of (−)-
trans-,(+)-trans-and (+)-cis-disparlures has been described. The pivotal reaction sequence …

Formal Synthesis of Sex Pheromone of Gypsy Moth (+)-Disparlure from L-(+)-Tartaric Acid

GB Gwon, HS Kim, JW Park, JS Choi… - Journal of the Korean …, 2024 - koreascience.kr
A simple strategy for the formal synthesis of the sex pheromone of gypsy moth (+)-disparlure
from L-(+)-tartaric acid is described herein. The key steps include the mono-esterification …

[PDF][PDF] Enantioselective synthesis of (-)-(5R, 6S)-6-acetoxyhexadecan-5-olide via tandem α-aminooxylation-Henry reaction

R Pandey, Y Garg, R Prakash, SK Pandeya - Organic Chemistry, 2018 - academia.edu
A novel enantioselective synthetic approach of (-)-(5R, 6S)-6-acetoxyhexadecan-5-olide, an
oviposition attractant pheromone of the mosquito Culex pipiens fatigans is presented …

Applications of enantioselective halolactonization reactions, synthesis of photocaged compounds for identifying neurons based on function, and progress towards the …

DW Klosowski - 2018 - repositories.lib.utexas.edu
Recently the Martin group developed a bifunctional organic catalyst that promotes highly
efficient enantioselective halolactonization reactions for olefinic acids. Using the BINOL …