Nitrene‐transfer reactions are powerful synthetic tools for the direct incorporation of nitrogen
atoms into organic molecules. The discovery of novel nitrene‐transfer reactions has been …

The azide moiety is a desirable functionality in organic molecules, useful in a variety of
transformations such as olefin aziridination, C–H bond amination, isocyanate synthesis, the …

We report here the synthesis of robust and porous metal–organic frameworks (MOFs), M-
MTBC (M= Zr or Hf), constructed from the tetrahedral linker methane-tetrakis (p …

Azoarenes are the largest class of photoswitching molecules, and they have a broad range
of applications in photopharmacology and materials science. Azoarenes possessing ortho …

Azoarenes are valuable chromophores that have been extensively incorporated as
photoswitchable elements in molecular machines and biologically active compounds. Here …

Distinguishing the reactivity differences between N2 complexes having different binding
modes is crucial for the design of effective N2-functionalizing reactions. Here, we compare …

A dianionic tetrapodal pentadentate diborate ligand is introduced. This ligand forms a high
spin neutral iron (II) complex that reacts with a variety of organoazides to yield transient Fe …

The formally CoIV carbene Co (OR) 2 ( CPh2) is formed upon the reaction of
diphenyldiazomethane with the cobalt bis (alkoxide) precursor Co (OR) 2 (THF) 2. Structural …

Abstract Die Umsetzung des CoI‐Komplexes [(TIMMNmes) CoI](PF6)(1)(TIMMNmes= tris‐[2‐
(3‐Mesityl‐imidazolin‐2‐yliden)‐methyl] amin) mit Mesitylazid ergibt das CoIII‐Imid …

Iron terminal imido species featuring electron-withdrawing N-substituents represent an
important category of reactive metal-ligand-multiple-bond intermediates in iron-catalyzed …