Solvent-free heterocyclic synthesis

MAP Martins, CP Frizzo, DN Moreira, L Buriol… - Chemical …, 2009 - ACS Publications
Heterocycles form, by far, the largest of the classical divisions of organic chemistry.
Moreover, they are of immense importance not only biologically and industrially but also to …

Recent developments in asymmetric alkynylations

V Bisai, VK Singh - Tetrahedron Letters, 2016 - Elsevier
Catalytic asymmetric syntheses of enantioenriched propargyl alcohols and amines have
been a central topic in organic synthesis. Toward this, a great deal of research has been put …

[HTML][HTML] The enantioselective addition of alkyne nucleophiles to carbonyl groups

BM Trost, AH Weiss - Advanced synthesis & catalysis, 2009 - ncbi.nlm.nih.gov
Over the past decade, large strides have been achieved in the invention of methods for the
direct enantioselective addition of alkynes and metal alkynylide nucleophiles into prochiral …

Phosphine-triggered complete chemo-switch: from efficient aldehyde− alkyne− amine coupling to efficient aldehyde− alkyne coupling in water

X Yao, CJ Li - Organic letters, 2005 - ACS Publications
A phosphine ligand served as a remarkable chemo-switch for the silver-catalyzed reaction of
alkynes with aldehydes in the presence of amines in water. Exclusive aldehyde− alkyne …

Bisoxazolidine-catalyzed enantioselective alkynylation of aldehydes

C Wolf, S Liu - Journal of the American Chemical Society, 2006 - ACS Publications
A C2-symmetric bisoxazolidine derived from aminoindanol has been successfully applied in
the asymmetric alkynylation of aldehydes. The ligand is readily available, has a wide …

Asymmetric addition of diorganozinc reagents to aldehydes and ketones

CM Binder, B Singaram - Organic Preparations and Procedures …, 2011 - Taylor & Francis
The direct addition of organometallic reagents to carbonyl compounds is an efficient and
versatile method to generate CC bonds with concomitant formation of secondary and tertiary …

Asymmetric catalysis with chiral oxazolidine ligands

C Wolf, H Xu - Chemical Communications, 2011 - pubs.rsc.org
Asymmetric catalysis with chiral 1, 3-oxazolidine ligands, which have a sterically tunable,
rigid structure that can accommodate several chiral centers, has found increasing attention …

Evaluation of Enantiopure N-(Ferrocenylmethyl)azetidin-2-yl(diphenyl)methanol for Catalytic Asymmetric Addition of Organozinc Reagents to Aldehydes

MC Wang, QJ Zhang, WX Zhao, XD Wang… - The Journal of …, 2008 - ACS Publications
A facile and practical approach to preparation of enantiopure N-(ferrocenylmethyl) azetidin-2-
yl (diphenyl) methanol was developed from cheap and easily available l-(+)-methionine …

Enantioselective alkynylation of aldehydes with 1-haloalkynes catalyzed by tethered bis (8-quinolinato) chromium complex

DL Usanov, H Yamamoto - Journal of the American Chemical …, 2011 - ACS Publications
The first example of Cr-catalyzed asymmetric alkynylation of aldehydes with 1-iodo-and 1-
bromoalkynes was developed. The use of tethered bis (8-quinolinato) chromium catalyst (3 …

Synergistic effect of GO/SrFe 12 O 19 as magnetic hybrid nanocatalyst for regioselective ring-opening of epoxides with amines under eco-friendly conditions

M Laayati, AA Mekkaoui, L Fkhar, MA Ali, H Anane… - RSC …, 2022 - pubs.rsc.org
Herein, a highly efficient magnetically separable hybrid GO/SrFe12O19 nanocomposite was
synthesized via dispersing M-type strontium hexaferrite (SrFe12O19) on graphene oxide …