Cycloaromatization of Open and Masked 1, 3‐Hexadien‐5‐ynes− Mechanistic and Synthetic Aspects

G Zimmermann - European Journal of Organic Chemistry, 2001 - Wiley Online Library
The discovery of the net‐cyclization of 1, 3‐hexadien‐5‐yne to benzene at temperatures
around 250° C was followed, particularly during the 1990s, by an increasing number of …

Some developments in the high temperature gas phase chemistry of alkynes, arynes and aryl radicals

RF C. Brown - European journal of organic chemistry, 1999 - Wiley Online Library
The discovery of the equilibration of alkynes with ylidenecarbenes at high temperatures has
been followed by increasing use of the reactivity of such carbenes in the synthesis of …

1, 2-shifts of hydrogen atoms in aryl radicals

MA Brooks, LT Scott - Journal of the American Chemical Society, 1999 - ACS Publications
An energy barrier on the order of 60 kcal/mol is predicted for the 1, 2-shift of hydrogen atoms
in aryl radicals. Such rearrangements are, therefore, not expected to occur under ordinary …

Strain-free sextet-resonant benzenoids and their antisextet dualists

AT Balaban, TG Schmalz - Journal of chemical information and …, 2006 - ACS Publications
By introducing antisextet dualists of sextet-resonant benzenoids that have only “full” and
“empty” rings as defined by Clar, it was possible to devise a simple algorithm for an …

Cannabinoid receptor modulators

S Chackalamannil, MV Chelliah, MC Clasby… - US Patent …, 2011 - Google Patents
2007-05-09 Assigned to SCHERING CORPORATION reassignment SCHERING
CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR …

Thermolysis of benzo [c] phenanthrene-5, 6-dicarboxylic anhydride and 6H-benzo [cd] pyren-6-one. Entries to the combustion effluents benzo [ghi] fluoranthene and …

M Sarobe, LW Jenneskens, UE Wiersum - Tetrahedron letters, 1997 - Elsevier
Thermolysis of Benzo[c]phenanthrene-5,6-dicarboxylic Anhydride and 6H-Benzo[cd]pyren-6.one.
Entries to the Combustion Effluents Page 1 Tetrahedron Letters, Vol. 38, No. 26, pp. 4689-4692 …

Flow-vacuum pyrolysis of 5-methylene-5H-dibenzo [a, d] cycloheptene

MD Banciu, C Costea, C Draghici, A Banciu… - Journal of analytical and …, 2003 - Elsevier
The flow-vacuum pyrolyses of 5-methylene-5H-dibenzo [a, d] cycloheptene (11) were
studied by GC/MS at 1.33 mbar and temperatures between 750 and 1050° C. The major …

Pyrolytic electrocyclization of arylmethylidene derivatives of glutacononitrile; synthesis of dihydroaromatic 1, 3-dinitriles

MD Banciu, RFC Brown, KJ Coulston… - Australian journal of …, 1998 - CSIRO Publishing
Condensation of seven aromatic aldehydes (1a–g) with glutacononitrile (2) gave 4-
(arylmethylidene) pent-2-enedinitriles (3a–g). Flash vacuum pyrolysis of the dinitriles (3a–g) …

[图书][B] Chemistry of angular and linear [N] phenylenes

PI Dosa - 2002 - search.proquest.com
This dissertation discusses several topics relating to the [N] phenylenes, including their
behavior under flash vacuum pyrolysis conditions, and the structural characterizations of …

Remembering Roger FC Brown: A Personal Note on the Development of Pyrolysis as a Synthetic and Mechanistic Technique in Organic Chemistry

UE Wiersum - Australian Journal of Chemistry, 2014 - hero.epa.gov
UE Wiersum, while remembering Professor Robert Brown, describes a note on the
development of pyrolysis as a synthetic and mechanistic technique in organic chemistry. In …