Monofluoroalkenes have found wide application in organic chemistry, medicinal chemistry,
and materials science. This review summarizes the most recent advances made regarding …

A simple formylation reaction of aryl halides, aryl triflates, and vinyl bromides under
synergistic nickel‐and organic‐dye‐mediated photoredox catalysis is reported. Distinct from …

α-Functionalized α, β-unsaturated aldehydes is an important class of compounds, which are
widely used in fine organic synthesis, biology, medicine and pharmacology, chemical …

A unique domino reaction of enolizable carbonyl compounds with Me3SiCF2Br to construct
α-fluoroenones and α-fluoroenals is described to undergo the in situ formation of …

The first example of stereoconvergent 1, 3-dipolar cycloaddition of nitrile oxides and nitrile
imines with E/Z isomeric mixture of electron-deficient olefins is reported, delivering …

Various alkenes are formylated with dichloromethyl methyl ether (MOMCl2) by the combined
use of SnCl4/2, 6-dibromopyridine (B1) or AgOTf/pyridine (B4) via Friedel–Crafts-type …

The CO2-mediated hydroxylation of gem-difluorocyclopropanes is herein described, under
Pd (0) catalysis in the presence of H2O. The method affords a large series of valuable …

Ring-opening amination of gem-chlorofluoro-and gem-bromofluorocyclopropanes with
secondary alkyl, aryl amines or hydroxylamines catalyzed by copper (I) or copper (II) …

The importance of organofluorine compounds in pharmaceuticals and agrochemicals has
encouraged the study of their synthesis since the middle of the twentieth century. In recent …

Copper (I)-catalyzed solvolysis of gem-chlorofluoro-and gem-bromofluorocyclopropanes in
MeOH, NaOAc/AcOH, NaOAc/DMF, HCO 2 Na/HCO 2 H or water/dioxane affords 2 …