The development of the first intermolecular Rh2 (II)-catalyzed aziridination of olefins using
anilines as nonactivated N atom precursors and an iodine (III) reagent as the stoichiometric …

Carbon–hydrogen bond functionalization methods are important tools for efficiently
upgrading simple precursors to more valuable compounds. The ubiquity of amines in …

Azepines and their saturated azepane counterparts are important moieties in bioactive
molecules but are under-represented in current drug screening libraries. Herein, we report a …

Sulfamates and sulfamides are most often synthesized from alcohols and amines with
sulfamoyl chloride, which is an unstable reagent. We have identified hexafluoroisopropyl …

Selective amination of σ and π entities such as C–H and C═ C bonds of substrates remains
a challenging endeavor for current catalytic methodologies devoted to the synthesis of …

The tripodal compounds [(TMG3trphen) MII–solv](PF6) 2 (M= Mn, Fe, Co; solv= MeCN, DMF)
and bipodal analogues [(TMG2biphen) MII (NCMe) x](PF6) 2 (x= 3 for Mn, Fe; x= 2 for Co) …

We describe the imidation of phosphines and α-amidation of 1, 3-dicarbonyl compounds
using N-triflylimino-λ3-iodane, which is generated in situ from iodosylarene and triflylamide …

Recent research has highlighted the key role played by the electron affinity of the active
metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford …

Iodonium imides (ArINR) represent an important class of hypervalent iodine (III) compounds
recently emerging as versatile, efficient and environmentally friendly synthetic reagents with …

The bipodal compounds [(TMG2biphenN-R) CuI–NCMe](PF6)(R= Me, Ar (4-CF3Ph-)) and
[(TMG2biphenN-Me) CuI–I] have been synthesized with ligands that feature a diarylmethyl …