Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials

OS Hammond, AV Mudring - Chemical Communications, 2022 - pubs.rsc.org
Ionic liquids (ILs) are becoming a revolutionary synthesis medium for inorganic
nanomaterials, permitting more efficient, safer and environmentally benign preparation of …

Targeted modifications in ionic liquids–from understanding to design

F Philippi, T Welton - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Ionic liquids are extremely versatile and continue to find new applications in academia as
well as industry. This versatility is rooted in the manifold of possible ion types, ion …

Modern room temperature ionic liquids, a simple guide to understanding their structure and how it may relate to dynamics

JC Araque, JJ Hettige, CJ Margulis - The Journal of Physical …, 2015 - ACS Publications
Modern room temperature ionic liquids are structurally defined by symmetries on different
length scales. Polar–apolar alternation defines their nanoscale structural heterogeneity …

Structure and aggregation in the 1-alkyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ionic liquid homologous series

K Shimizu, CES Bernardes… - The Journal of Physical …, 2014 - ACS Publications
A new comprehensive Molecular Dynamics study using large simulation boxes has been
performed in order to complete and extend the structural analysis on the mesoscopic …

The magic of aqueous solutions of ionic liquids: ionic liquids as a powerful class of catanionic hydrotropes

AFM Cláudio, MC Neves, K Shimizu, JNC Lopes… - Green …, 2015 - pubs.rsc.org
Hydrotropes are compounds able to enhance the solubility of hydrophobic substances in
aqueous media and therefore are widely used in the formulation of drugs, cleaning and …

Simulations of room temperature ionic liquids: from polarizable to coarse-grained force fields

M Salanne - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
Room temperature ionic liquids (RTILs) are solvent with unusual properties, which are
difficult to characterize experimentally because of their intrinsic complexity (large number of …

Asymmetric composition of ionic aggregates and the origin of high correlated transference number in water-in-salt electrolytes

Z Yu, LA Curtiss, RE Winans, Y Zhang… - The Journal of …, 2020 - ACS Publications
“Water-in-salt” electrolytes open up exciting new avenues for expanding the electrochemical
window of aqueous electrolytes. We investigated the solvation structure and dynamics of …

Triphilic Ionic‐Liquid Mixtures: Fluorinated and Non‐fluorinated Aprotic Ionic‐Liquid Mixtures

O Hollóczki, M Macchiagodena, H Weber… - …, 2015 - Wiley Online Library
We present here the possibility of forming triphilic mixtures from alkyl‐and
fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which …