Albeit the first account of hypervalent⋯ π interactions has been reported with halogen⋯ π
interactions, the feasibility of their extension to other hypervalent atoms as possible Lewis …

Conformational isomerism of trimethylphosphate (TMP) has been studied de novo. TMP
monomers were isolated in low temperature xenon matrices at different substrate …

NIR-FT Raman and FT-IR spectra of columbianadin, extracted from seeds and roots of
Heracleum candolleaum, were recorded and analyzed. The vibrational frequencies of the …

Hydrogen bonded H⋯ π complexes of C2H2 and C6H6 were studied both computationally
and experimentally. Computationally, C2H2–C6H6 complexes of 1: 1 and 2: 1 …

The hydrogen-bond interaction between formic acid and acetylene was studied by matrix
isolation infrared spectroscopy coupled with ab initio computations. The 1: 1 adduct of formic …

The adducts of phosphoryl chloride (POCl 3) and methanol (CH 3 OH) were studied using
matrix isolation infrared spectroscopy and DFT calculations. The 1: 1 POCl 3: CH 3 OH …

Trimethyl phosphite (TMPhite) and hydrogen chloride (HCl), when separately codeposited in
a N2 matrix, yielded a hydrogen bonded adduct, which was evidenced by shifts in the …

Weak hydrogen bonds formed by 2-and 3-ethynylpyridine and ethynylbenzene with
trimethylphosphate and phenol were characterized by IR spectroscopy and DFT calculations …

Trimethyl phosphate (TMP) and fluoroform (CHF3) were co-deposited in a nitrogen matrix
and complexes of these species were identified using infrared spectroscopy. Formation of …

Matrix isolation spectroscopy in combination with ab initio calculations is a powerful
technique for the identification of weakly bound intermolecular complexes. Here, weak …