Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Transition metal‐free sulfenylation of C− H bonds for C− S bond formation in recent years: Mechanistic approach and promising future

M Saroha, J Sindhu, S Kumar, KK Bhasin… - …, 2021 - Wiley Online Library
Transition metal‐free sulfenylation of C− H bonds for C− S bond formation has recently
emerged as sustainable protocols for the functionalisation of various molecules …

Ambient and aerobic carbon–carbon bond cleavage toward α-ketoester synthesis by transition-metal-free photocatalysis

Q Yu, Y Zhang, JP Wan - Green Chemistry, 2019 - pubs.rsc.org
The α-oxoesterification of the CC double bond in readily available enaminones enabling
efficient synthesis of α-ketoesters is developed. The reactions showing general tolerance to …

Cutting edge of diphenyl phosphorazidate (DPPA) as a synthetic reagent–A fifty-year odyssey

T Shioiri, K Ishihara, M Matsugi - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Recent advances of diphenyl phosphorazidate (DPPA) as a versatile synthetic reagent was
described. It works as an azide anion equivalent, 1, 3-dipole, electrophile, and nitrene. Thus …

Dehalogenative Deuteration of Unactivated Alkyl Halides Using D2O as the Deuterium Source

A Xia, X Xie, X Hu, W Xu, Y Liu - The Journal of Organic Chemistry, 2019 - ACS Publications
The general dehalogenation of alkyl halides with zinc using D2O or H2O as a deuterium or
hydrogen donor has been developed. The method provides an efficient and economic …

Metal-free oxidative thioesterification of methyl ketones with thiols/disulfides for the synthesis of α-ketothioesters

B Hu, P Zhou, Q Zhang, Y Wang, S Zhao… - The Journal of …, 2018 - ACS Publications
A direct Csp3–H bond oxidative thioesterification of methyl ketones with aromatic
thiols/disulfides promoted by TBAI/K2S2O8 has been developed. The reaction provides …

Controlled Ni-catalyzed mono-and double-decarbonylations of α-ketothioesters

ZJ Zheng, C Jiang, PC Shao, WF Liu, TT Zhao… - Chemical …, 2019 - pubs.rsc.org
A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono-
and double-decarbonylations, which gave thioesters and thioethers, respectively, were …

Visible-Light-Activated Divergent Reactivity of Dienones: Dimerization in Neat Conditions and Regioselective E to Z Isomerization in the Solvent

S Naskar, S Roy Chowdhury, S Mondal, DK Maiti… - Organic …, 2019 - ACS Publications
2, 4-Dienones undergo visible-light-promoted, photocatalyst-free dimerization in neat
conditions to provide cyclohexene derivatives stereoselectively through cascade …

CuO-decorated magnetite-reduced graphene oxide: a robust and promising heterogeneous catalyst for the oxidative amidation of methylarenes in water via benzylic …

M Rousta, D Khalili, A Khalafi-Nezhad… - New Journal of …, 2021 - pubs.rsc.org
A magnetite-reduced graphene oxide-supported CuO nanocomposite (rGO/Fe3O4–CuO)
was prepared via a facile chemical method and characterized by Fourier-transform infrared …

Sonochemically-promoted preparation of silica-anchored cyclodextrin derivatives for efficient copper catalysis

K Martina, F Calsolaro, A Zuliani, G Berlier… - Molecules, 2019 - mdpi.com
Silica-supported metallic species have emerged as valuable green-chemistry catalysts
because their high efficiency enables a wide range of applications, even at industrial scales …