Bisimine derivatives of salicylaldehyde with chiral diamines (salens) are privileged ligands
in asymmetric organometallic catalysis, which can be used in cooperation with …

Carbon dioxide (CO 2) is an important and appealing C1 building block in chemical
synthesis due to its nontoxicity, abundance, availability and sustainability. Tremendous …

The combination of a chromium (III) salophen bromide complex and tetrabutylammonium
bromide is shown to catalyze the reaction between terminal epoxides and carbon dioxide at …

The development of inexpensive and sustainable aluminum (salen) complexes as catalysts
for the kinetic resolution of terminal epoxides is described. The kinetic resolution is carried …

A salen based molecular cage, salen@ cage, was synthesized and complexed with Co and
Al to yield metal–salen molecular cages, Co (II)@ cage, Co (III)@ cage and Al (III)@ cage …

A bifunctional cationic porous organic polymer based on a Salen-(Al) metalloligand (Al-
CPOP) containing imidazolium functionality exhibited enhanced activity and good …

Tetrabutylammonium hydroxide (TBAH) and other quaternary ammonium hydroxides
catalyzed the cycloaddition of CO2 to epoxides under solvent-free conditions to give cyclic …

A bimetallic aluminium (salphen) complex is reported as a sustainable, efficient and
inexpensive catalyst for the synthesis of cyclic carbonates from epoxides and carbon …

This review summarizes the advances in catalytic enantioselective reactions using CO2 as a
C1 synthon, introduces major synthetic strategies and discusses their advantages and …

A series of inexpensive and sustainable amidinate aluminium complexes has been
developed as catalysts for the chemical fixation of carbon dioxide into cyclic carbonates. The …